<abstract xmlns="http://www.w3.org/1999/xhtml">The composite containing nanosilver uniformly deposited on matrix composed of CaHPO4 x 2H2O (brushite, <italic>ca</italic> 89 mass %), CaHPO4 (monteonite, <italic>ca</italic> 9.5 mass%), and Ag3PO4 (0.5 mas%) was obtained by addition of calcium nitrate and silver nitrate aqueous solution at 30:1 Ca:Ag molar ratio into excess of (NH4)2PO4 solution at pH 5.0 – 5.5. The isolated solid was characterized by STEM, XRD, and LDI mass spectrometry. It has been found that nanosilver was uniformly distributed within composite as &lt;10 nm diameter sized nanoparticles. Determination of silver by AAS showed that 60% of silver is present as Ag(0) nanoparticles, the present as matrix Ag3PO4 as identified by XRD method. The composite showed strong growth inhibition in <italic>E. coli</italic> and <italic>P. aeruginosa</italic> strains, and moderate towards <italic>S. aureus</italic>. The <italic>C. albicans</italic> cells were the most resistant to the tested material, although still composite was moderately cytostatic for the yeast.</abstract>

The composite containing nanosilver uniformly deposited on matrix composed of CaHPO4 x 2H2O (brushite, ca 89 mass %), CaHPO4 (monteonite, ca 9.5 mass%), and Ag3PO4 (0.5 mas%) was obtained by addition of calcium nitrate and silver nitrate aqueous solution at 30:1 Ca:Ag molar ratio into excess of (NH4)2PO4 solution at pH 5.0 – 5.5. The isolated solid was characterized by STEM, XRD, and LDI mass spectrometry. It has been found that nanosilver was uniformly distributed within composite as <10 nm diameter sized nanoparticles. Determination of silver by AAS showed that 60% of silver is present as Ag(0) nanoparticles, the present as matrix Ag3PO4 as identified by XRD method. The composite showed strong growth inhibition in E. coli and P. aeruginosa strains, and moderate towards S. aureus. The C. albicans cells were the most resistant to the tested material, although still composite was moderately cytostatic for the yeast.

Silver nanoparticles deposited on calcium hydrogenphosphate – silver phosphate matrix; biological activity of the composite

Faculty of Mathematics and Natural Sciences

Polish Journal of Chemical Technology

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

The composite containing nanosilver uniformly deposited on matrix composed of CaHPO4 x 2H2O (brushite, ca 89 mass %), CaHPO4 (monteonite, ca 9.5 mass%), and...

Silver nanoparticles deposited on calcium hydrogenphosphate – silver phosphate matrix; biological activity of the composite

Published Online: Jun 28, 2019

Page range: 6 - 13

DOI: https://doi.org/10.2478/pjct-2019-0013

Keywords
silver nanoparticles, composite, calcium hydrogenphosphate matrix, electron microscopy, mass spectrometry

© 2019 K. Szmuc et al., published by Sciendo

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Silver nanoparticles deposited on calcium hydrogenphosphate – silver phosphate matrix; biological activity of the composite

Published Online: Jun 28, 2019

Page range: 6 - 13

DOI: https://doi.org/10.2478/pjct-2019-0013

Keywordssilver nanoparticles, composite, calcium hydrogenphosphate matrix, electron microscopy, mass spectrometry

© 2019 K. Szmuc et al., published by Sciendo

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Keywords
silver nanoparticles, composite, calcium hydrogenphosphate matrix, electron microscopy, mass spectrometry