Kinetic Parameters for the Thermal Decomposition of Forest Waste Using Distributed Activation Energy Model (DAEM)

The purview of paper pivoted around the pyrolysis decomposition of forest waste (pine needle litter) by thermogravimetric analysis (TGA). Experiments were carried out in the presence of Nitrogen atmosphere. The experimental data was compared with those obtained by numerical solution of distributed activation energy model (DAEM). Asymptotic expansion is adopted to evaluate the pre-exponential factor, mean activation energy and variance. The correction factor B_i has been invoked to describe accurately the differential thermogravitmeric curves of thermal decomposition of pine needles.