Phenomenological Variant of Quasi-Chemical Approximation in the Description of the Dimerisation of Adsorbate Molecules in a Multilayer Adsorption Phase on a Homogeneous Surface

This article is related thematically to two of our earlier publications, which demonstrated full equivalence of statistical and phenomenological methods in the description of physical gas adsorption on the surface of a solid body, and the fundamental possibility of analytical solution of adsorbate-adsorbate association problems in the entire multi-layer adsorption phase. The quasi-chemical scheme of secondary interactions leading to the formation of horizontal multimolecular adsorption complexes has been elaborated. A new adsorption equation was formulated taking into account the dimerisation of adsorbed molecules in the whole adsorption phase, as well as the influence of topography of the binding sites of adsorbent surfaces on the form of this solution.