<abstract xmlns="http://www.w3.org/1999/xhtml"><p>This article is related thematically to two of our earlier publications, which demonstrated full equivalence of statistical and phenomenological methods in the description of physical gas adsorption on the surface of a solid body, and the fundamental possibility of analytical solution of adsorbate-adsorbate association problems in the entire multi-layer adsorption phase. The quasi-chemical scheme of secondary interactions leading to the formation of horizontal multimolecular adsorption complexes has been elaborated. A new adsorption equation was formulated taking into account the dimerisation of adsorbed molecules in the whole adsorption phase, as well as the influence of topography of the binding sites of adsorbent surfaces on the form of this solution.</p></abstract>

This article is related thematically to two of our earlier publications, which demonstrated full equivalence of statistical and phenomenological methods in the description of physical gas adsorption on the surface of a solid body, and the fundamental possibility of analytical solution of adsorbate-adsorbate association problems in the entire multi-layer adsorption phase. The quasi-chemical scheme of secondary interactions leading to the formation of horizontal multimolecular adsorption complexes has been elaborated. A new adsorption equation was formulated taking into account the dimerisation of adsorbed molecules in the whole adsorption phase, as well as the influence of topography of the binding sites of adsorbent surfaces on the form of this solution.

Phenomenological Variant of Quasi-Chemical Approximation in the Description of the Dimerisation of Adsorbate Molecules in a Multilayer Adsorption Phase on a Homogeneous Surface

University of Technology and Life Sciences in Bydgoszcz

Nicolaus Copernicus University in Torun L. Rydygier Collegium Medicum in Bydgoszcz

Department of Hygiene, Epidemiology and Ergonomics

Polish Hyperbaric Research

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.

This article is related thematically to two of our earlier publications, which demonstrated full equivalence of statistical and phenomenological methods in the...

Phenomenological Variant of Quasi-Chemical Approximation in the Description of the Dimerisation of Adsorbate Molecules in a Multilayer Adsorption Phase on a Homogeneous Surface

Published Online: Jan 10, 2020

Page range: 33 - 40

Received: May 19, 2019

Accepted: Jul 19, 2019

DOI: https://doi.org/10.2478/phr-2019-0011

Keywords
adsorption, surface homogeneity, adsorbate-adsorbate association, adsorption multiple layers

© 2019 Jerzy K. Garbacz et al., published by Sciendo

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.

Phenomenological Variant of Quasi-Chemical Approximation in the Description of the Dimerisation of Adsorbate Molecules in a Multilayer Adsorption Phase on a Homogeneous Surface

Published Online: Jan 10, 2020

Page range: 33 - 40

Received: May 19, 2019

Accepted: Jul 19, 2019

DOI: https://doi.org/10.2478/phr-2019-0011

Keywordsadsorption, surface homogeneity, adsorbate-adsorbate association, adsorption multiple layers

© 2019 Jerzy K. Garbacz et al., published by Sciendo

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.

Keywords
adsorption, surface homogeneity, adsorbate-adsorbate association, adsorption multiple layers