<abstract xml:lang="en" xmlns="http://www.w3.org/1999/xhtml"><p>The influence of technological parameters on the transformation of 1-butene-3-ol (1B3O) to bis(3-methyl-1-propene) ether (2×1B3O ether) and 3-(3-methyl-1-propene)-3-methyl-1,2-epoxypropane ether (1B3Ox1,2EB3O ether) over the TS-2 catalyst was presented. The reaction was performed in a glass reactor at atmospheric pressure and in methanol medium (protic solvent). The optimum conditions of 2×1B3O ether and 1B3Ox1,2EB3O ether obtaining were established by the mathematical method of experiments design (rotatable-uniform design) and after the analyses of the layer drawings.</p></abstract>

The influence of technological parameters on the transformation of 1-butene-3-ol (1B3O) to bis(3-methyl-1-propene) ether (2×1B3O ether) and 3-(3-methyl-1-propene)-3-methyl-1,2-epoxypropane ether (1B3Ox1,2EB3O ether) over the TS-2 catalyst was presented. The reaction was performed in a glass reactor at atmospheric pressure and in methanol medium (protic solvent). The optimum conditions of 2×1B3O ether and 1B3Ox1,2EB3O ether obtaining were established by the mathematical method of experiments design (rotatable-uniform design) and after the analyses of the layer drawings.

Bis(3-methyl-1-propene) ether and 3-(3-methyl-1-propene)-3-methyl-1,2-epoxypropane ether synthesis during the epoxidation of 1-butene-3-ol with hydrogen peroxide over the TS-2 catalyst

Institute of Organic Chemical Technology, West Pomeranian University of Technology, ul. Pułaskiego 10, 70-322 Szczecin, Poland

Polish Journal of Chemical Technology

The influence of technological parameters on the transformation of 1-butene-3-ol (1B3O) to bis(3-methyl-1-propene) ether (2×1B3O ether) and...

Bis(3-methyl-1-propene) ether and 3-(3-methyl-1-propene)-3-methyl-1,2-epoxypropane ether synthesis during the epoxidation of 1-butene-3-ol with hydrogen peroxide over the TS-2 catalyst

Publié en ligne: 27 sept. 2010

Pages: 66 - 71

DOI: https://doi.org/10.2478/v10026-010-0037-7

Mots clés
bis(3-methyl-1-propene) ether, 3-(3-methyl-1-propene)-3-methyl-1,2-epoxypropane ether, TS-2, hydrogen peroxide, epoxidation in liquid phase

This content is open access.

Bis(3-methyl-1-propene) ether and 3-(3-methyl-1-propene)-3-methyl-1,2-epoxypropane ether synthesis during the epoxidation of 1-butene-3-ol with hydrogen peroxide over the TS-2 catalyst

Publié en ligne: 27 sept. 2010

Pages: 66 - 71

DOI: https://doi.org/10.2478/v10026-010-0037-7

Mots clésbis(3-methyl-1-propene) ether, 3-(3-methyl-1-propene)-3-methyl-1,2-epoxypropane ether, TS-2, hydrogen peroxide, epoxidation in liquid phase

This content is open access.

Mots clés
bis(3-methyl-1-propene) ether, 3-(3-methyl-1-propene)-3-methyl-1,2-epoxypropane ether, TS-2, hydrogen peroxide, epoxidation in liquid phase