<abstract xml:lang="en" xmlns="http://www.w3.org/1999/xhtml"><p>An influence of the molar ratio of <italic>cis, trans, trans</italic>-1,5,9-cyclododecatriene to <italic>tert</italic>-butyl hydroperoxide, the concentration of the catalyst and the reaction time on the performance of the epoxidation process of <italic>cis, trans, trans</italic>-1,5,9-cyclodecatriene with <italic>tert</italic>-butyl hydroperoxide at the presence of molybdenum hexacarbonyl Mo(CO)<sub>6</sub> was examined. Examinations were performed using statistical methods of the design of experiments. A mathematical model describing the influence of the parameters on conversion <italic>cis, trans, trans</italic>-1,5,9-cyclododecatriene was obtained. An analysis of the data and rests was performed and an optimal value of conversion of <italic>cis, trans, trans</italic>-1,5,9-cyclododecatriene was established.</p></abstract>

An influence of the molar ratio of cis, trans, trans-1,5,9-cyclododecatriene to tert-butyl hydroperoxide, the concentration of the catalyst and the reaction time on the performance of the epoxidation process of cis, trans, trans-1,5,9-cyclodecatriene with tert-butyl hydroperoxide at the presence of molybdenum hexacarbonyl Mo(CO)6 was examined. Examinations were performed using statistical methods of the design of experiments. A mathematical model describing the influence of the parameters on conversion cis, trans, trans-1,5,9-cyclododecatriene was obtained. An analysis of the data and rests was performed and an optimal value of conversion of cis, trans, trans-1,5,9-cyclododecatriene was established.

Application of the design of experiments in the epoxidation process of 1,5,9-cyclododecatriene

Institute of Organic Chemical Technology, Szczecin University of Technology, ul. Pułaskiego 10, 70-322 Szczecin, Poland

Polish Journal of Chemical Technology

An influence of the molar ratio of cis, trans, trans-1,5,9-cyclododecatriene to tert-butyl hydroperoxide, the concentration of the catalyst and the reaction...

Application of the design of experiments in the epoxidation process of 1,5,9-cyclododecatriene

Publié en ligne: 30 janv. 2008

Pages: 68 - 71

DOI: https://doi.org/10.2478/v10026-007-0093-9

Mots clés
epoxidation, design of experiments, 1,5,9-cyclododecatriene, optimization

This content is open access.

Application of the design of experiments in the epoxidation process of 1,5,9-cyclododecatriene

Publié en ligne: 30 janv. 2008

Pages: 68 - 71

DOI: https://doi.org/10.2478/v10026-007-0093-9

Mots clésepoxidation, design of experiments, 1,5,9-cyclododecatriene, optimization

This content is open access.

Mots clés
epoxidation, design of experiments, 1,5,9-cyclododecatriene, optimization