<abstract xml:lang="en" xmlns="http://www.w3.org/1999/xhtml">The optimization studies of the epoxidation process of (1Z,5E,9E)-1,5,9-cyclododecatriene (CDT) with tert-buthyl hydroperoxide (TBHP) over the molybdenum catalyst Mo(CO)6 were performed. The reaction was examined in terms of a uniform-rotatable design. Three factors were analyzed: the reaction time, CDT:TBHP molar ratio, and the molar concentration of the catalyst (Mo(CO)6). According to the design 20 experiments were performed at the constant temperature of 70°C.</abstract>

The optimization studies of the epoxidation process of (1Z,5E,9E)-1,5,9-cyclododecatriene (CDT) with tert-buthyl hydroperoxide (TBHP) over the molybdenum catalyst Mo(CO)6 were performed. The reaction was examined in terms of a uniform-rotatable design. Three factors were analyzed: the reaction time, CDT:TBHP molar ratio, and the molar concentration of the catalyst (Mo(CO)6). According to the design 20 experiments were performed at the constant temperature of 70°C.

Optimization of the epoxidation process of (1<italic>Z</italic>,5<italic>E</italic>,9<italic>E</italic>)-1,5,9-cyclododecatriene to 1,2-epoxy-(5<italic>Z</italic>,9<italic>E</italic>)-5,9-cyclododecadiene with <italic>tert</italic>-buthyl hydroperoxide — the influence of technological parameters on the hydroperoxide conversion

Institute of Organic Chemical Technology, Szczecin University of Technology, Pulaskiego 10, 70-322 Szczecin, Poland

Polish Journal of Chemical Technology

Optimization of the epoxidation process of (1,5,9)-1,5,9-cyclododecatriene to 1,2-epoxy-(5,9)-5,9-cyclododecadiene with -buthyl hydroperoxide — the influence of technological parameters on the hydroperoxide conversion

The optimization studies of the epoxidation process of (1Z,5E,9E)-1,5,9-cyclododecatriene (CDT) with tert-buthyl hydroperoxide (TBHP) over the molybdenum...

Optimization of the epoxidation process of (1Z,5E,9E)-1,5,9-cyclododecatriene to 1,2-epoxy-(5Z,9E)-5,9-cyclododecadiene with tert-buthyl hydroperoxide — the influence of technological parameters on the hydroperoxide conversion

Publié en ligne: 06 nov. 2007

Pages: 105 - 107

DOI: https://doi.org/10.2478/v10026-007-0066-z

Mots clés
epoxidation, -butyl hydroperoxide, (1,5,9)-1,5,9-cyclododecatriene, 1,2-epoxy-(5,9)-5,9-cyclododecadiene, design of experiments, optimization

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