<abstract xmlns="http://www.w3.org/1999/xhtml"><p>A novel 4-methylpyridinium 3-nitrophthalate (4MP3NP) was synthesized and the crystals were grown by using slow evaporation method. The structural data of the grown crystal was collected by single crystal X-ray diffraction. It revealed that the 4MP3NP crystal belongs to triclinic crystal system with a space group P1. Structure of the synthesized compound was established using SHELXL 97 program package. The crystalline nature and composition of the grown crystal was established using high resolution X-ray diffraction and FT-IR analyses. UV-Vis transmittance and photoluminescence studies revealed the optical transmission window and electronic transition mechanism of ions, respectively. The laser damage threshold of the grown crystal was estimated by Nd:YAG laser and these results were mutually related to specific heat capacity of the grown crystal. The third-order nonlinear optical susceptibility of the grown crystal was studied by Z-scan technique.</p></abstract>

A novel 4-methylpyridinium 3-nitrophthalate (4MP3NP) was synthesized and the crystals were grown by using slow evaporation method. The structural data of the grown crystal was collected by single crystal X-ray diffraction. It revealed that the 4MP3NP crystal belongs to triclinic crystal system with a space group P1. Structure of the synthesized compound was established using SHELXL 97 program package. The crystalline nature and composition of the grown crystal was established using high resolution X-ray diffraction and FT-IR analyses. UV-Vis transmittance and photoluminescence studies revealed the optical transmission window and electronic transition mechanism of ions, respectively. The laser damage threshold of the grown crystal was estimated by Nd:YAG laser and these results were mutually related to specific heat capacity of the grown crystal. The third-order nonlinear optical susceptibility of the grown crystal was studied by Z-scan technique.

Synthesis, growth, structural, thermal and third order nonlinear optical properties of novel organic single crystal: 4-methylpyridinium 3-nitrophthalate

Materials Science-Poland

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.

A novel 4-methylpyridinium 3-nitrophthalate (4MP3NP) was synthesized and the crystals were grown by using slow evaporation method. The structural data of the...

Synthesis, growth, structural, thermal and third order nonlinear optical properties of novel organic single crystal: 4-methylpyridinium 3-nitrophthalate

Publié en ligne: 01 févr. 2019

Pages: 597 - 608

Reçu: 31 mars 2017

Accepté: 21 juil. 2018

DOI: https://doi.org/10.2478/msp-2018-0082

Mots clés
crystal structure, growth from solution, thermal studies, laser damage threshold studies, nonlinear optical materials

© 2018 S. Reena Devi et al., published by Sciendo

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.

Synthesis, growth, structural, thermal and third order nonlinear optical properties of novel organic single crystal: 4-methylpyridinium 3-nitrophthalate

Publié en ligne: 01 févr. 2019

Pages: 597 - 608

Reçu: 31 mars 2017

Accepté: 21 juil. 2018

DOI: https://doi.org/10.2478/msp-2018-0082

Mots cléscrystal structure, growth from solution, thermal studies, laser damage threshold studies, nonlinear optical materials

© 2018 S. Reena Devi et al., published by Sciendo

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.

Mots clés
crystal structure, growth from solution, thermal studies, laser damage threshold studies, nonlinear optical materials