<abstract xmlns="http://www.w3.org/1999/xhtml">A method for the determination of aclonifen at a carbon paste electrode modified with tricresyl phosphate has been developed. The optimum electrochemical regime proved to be differential pulse voltammetry (DPV) in the negative potential range from −200 to −1600 mV. The optimum pH for the determination proved to be pH = 8. The calibration dependence is linear and the limit of detection achieved for the method was 2·10−6 mol/dm3. The method is fast, reliable and it is suitable for the detection of aclonifen in the concentration range from 2·10−6 to 1·10−4 mol/dm3.</abstract>

A method for the determination of aclonifen at a carbon paste electrode modified with tricresyl phosphate has been developed. The optimum electrochemical regime proved to be differential pulse voltammetry (DPV) in the negative potential range from −200 to −1600 mV. The optimum pH for the determination proved to be pH = 8. The calibration dependence is linear and the limit of detection achieved for the method was 2·10−6 mol/dm3. The method is fast, reliable and it is suitable for the detection of aclonifen in the concentration range from 2·10−6 to 1·10−4 mol/dm3.

A Voltammetric Technique Using A Modified Carbon Paste Electrode For The Determination Of Aclonifen

Institute for Nanomaterials, Advanced Technology and Innovation, Bendlova 1407/7, 461 17 Liberec, Czech Republic, phone +420485353876

Department of Analytical Chemistry, UNESCO Laboratory of Environmental Electrochemistry, Faculty of Science, Charles University of Prague, Hlavova 2030, Praha 2, Czech Republic

Ecological Chemistry and Engineering S

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

<trans-abstract xml:lang="pl" xmlns="http://www.w3.org/1999/xhtml">Opisano metodę oznaczania aklonifenu węglową elektrodą pastową, modyfikowaną za pomocą fosforanu trikrezylu. Optymalnym systemem elektrochemicznym w badanej metodzie jest woltamperometria pulsowo-różnicowa (DPV) w ujemnym zakresie napięć od −200 do −1600 mV. Optymalne pH badanej metody wynosi 8. Krzywa kalibracyjna ma charakter liniowy z granicą wykrywalności 2·10−6 mol/dm3. Opisana metoda jest szybka, niezawodna oraz przydatna do oznaczania aklonifenu w zakresie stężeń od 2·10−6 do 1·10−4 mol/dm3.</trans-abstract>

Opisano metodę oznaczania aklonifenu węglową elektrodą pastową, modyfikowaną za pomocą fosforanu trikrezylu. Optymalnym systemem elektrochemicznym w badanej metodzie jest woltamperometria pulsowo-różnicowa (DPV) w ujemnym zakresie napięć od −200 do −1600 mV. Optymalne pH badanej metody wynosi 8. Krzywa kalibracyjna ma charakter liniowy z granicą wykrywalności 2·10−6 mol/dm3. Opisana metoda jest szybka, niezawodna oraz przydatna do oznaczania aklonifenu w zakresie stężeń od 2·10−6 do 1·10−4 mol/dm3.

WOLTAMPEROMETRYCZNE OZNACZANIE AKLONIFENU WĘGLOWĄ ELEKTRODĄ PASTOWĄ ZA POMOCĄ FOSFORANU TRIKREZYLU

A method for the determination of aclonifen at a carbon paste electrode modified with tricresyl phosphate has been developed. The optimum electrochemical...

A Voltammetric Technique Using A Modified Carbon Paste Electrode For The Determination Of Aclonifen

Publié en ligne: 05 oct. 2015

Pages: 451 - 458

DOI: https://doi.org/10.1515/eces-2015-0026

Mots clés
voltammetry, carbon paste electrode, aclonifen, herbicide determination

© Vít Novotný et al.

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

A Voltammetric Technique Using A Modified Carbon Paste Electrode For The Determination Of Aclonifen

Publié en ligne: 05 oct. 2015

Pages: 451 - 458

DOI: https://doi.org/10.1515/eces-2015-0026

Mots clésvoltammetry, carbon paste electrode, aclonifen, herbicide determination

© Vít Novotný et al.

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Mots clés
voltammetry, carbon paste electrode, aclonifen, herbicide determination