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Fig. 1

(a) Single crystalline 1-inch TlBr ingot used in the study, (b) a diced and polished TlBr sample.
(a) Single crystalline 1-inch TlBr ingot used in the study, (b) a diced and polished TlBr sample.

Fig. 2

ICP-MS results of the raw material, and top and bottom samples of TlBr.
ICP-MS results of the raw material, and top and bottom samples of TlBr.

Fig. 3

XRD patterns for the top, middle, and bottom samples of TlBr.
XRD patterns for the top, middle, and bottom samples of TlBr.

Fig. 4

(a) Transmittance and (b) α2 vs. hν curves for the top, middle, and bottom samples of TlBr.
(a) Transmittance and (b) α2 vs. hν curves for the top, middle, and bottom samples of TlBr.

Fig. 5

I-V characteristics and resistivities of the top, middle, and bottom samples of TlBr.
I-V characteristics and resistivities of the top, middle, and bottom samples of TlBr.

Summary of the Al impurity concentrations, FWHM (full width at half-maximum) values from the main peaks in the XRD graphs, optical bandgaps, and resistivities of the three samples used in this study.

TopMiddle Bottom
Al impurity conc. [ppm]0.120.090.47
FWHM [radian]0.2150.1560.223
Optical bandgap [eV]2.792.762.78
Resistivity [×1011 Ω·cm]2.22.52.2

Summary of the major impurities observed in the raw material and in the three samples, which were measured using an ICP-MS.

Unit [ppm]NaCaMgFeAlSiGaKIn
Raw material2.005.000.203.000.502.000.200.100.10
Top0.000.000.010.150.120.000.000.000.00
Middle0.000.000.000.040.090.000.000.000.00
Bottom0.000.000.040.220.470.000.000.000.00
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Materials Sciences, other, Nanomaterials, Functional and Smart Materials, Materials Characterization and Properties