<abstract xmlns="http://www.w3.org/1999/xhtml"><p>The synthesis and characterization of MCM-41 supported Co-Mo catalysts and catalytic hydrogenation of 1-octene to n-octane were discussed. BET specific surface area of MCM-41, calculated from N2 adsorption/desorption isotherm, was 1690 m2/g. The XRD patterns of the Co-Mo/MCM-41 catalysts show that metal species are finely dispersed and the size of CoO and MoO3 particles is below the detection limit by XRD. The 1-octene hydrogenation activity of the catalysts decreased with increasing the Co content up to 9 wt.% for the Co-promoted Co-Mo/MCM-41 catalysts with a MoO3 content of 12 wt.%. All the catalysts show increased hydrogenation activity with increasing reaction temperature in the temperature range from 200 to 350°C.</p></abstract>

The synthesis and characterization of MCM-41 supported Co-Mo catalysts and catalytic hydrogenation of 1-octene to n-octane were discussed. BET specific surface area of MCM-41, calculated from N2 adsorption/desorption isotherm, was 1690 m2/g. The XRD patterns of the Co-Mo/MCM-41 catalysts show that metal species are finely dispersed and the size of CoO and MoO3 particles is below the detection limit by XRD. The 1-octene hydrogenation activity of the catalysts decreased with increasing the Co content up to 9 wt.% for the Co-promoted Co-Mo/MCM-41 catalysts with a MoO3 content of 12 wt.%. All the catalysts show increased hydrogenation activity with increasing reaction temperature in the temperature range from 200 to 350°C.

Hydrogenation of 1-octene by Co-Mo/MCM-41 catalysts

Department of Petroleum Processing Engineering, Faculty of Petroleum Technology, Hamhung University of Chemical Industry, Str. Jongsong, Hamhung, D. P. R. of Korea

Department of Petroleum Processing Engineering and Environmental Protection, Faculty of Petroleum Technology and Petrochemistry, Petroleum-Gas University of Ploieşti, Bd. Bucureşti 39, 100680, Ploieşti, Romania

Ovidius University Annals of Chemistry

{"article-title":"Hydrogenation of 1-octene by Co-Mo/MCM-41 catalysts"}

The synthesis and characterization of MCM-41 supported Co-Mo catalysts and catalytic hydrogenation of 1-octene to n-octane were discussed. BET specific surface...

Hydrogenation of 1-octene by Co-Mo/MCM-41 catalysts

Online veröffentlicht: 22. März 2013

Seitenbereich: 133 - 136

DOI: https://doi.org/10.2478/v10310-012-0022-5

Schlüsselwörter
1-octene conversion, XRD, Co-Mo/MCM-41, BET specific surface area

This content is open access.

Hydrogenation of 1-octene by Co-Mo/MCM-41 catalysts

Online veröffentlicht: 22. März 2013

Seitenbereich: 133 - 136

DOI: https://doi.org/10.2478/v10310-012-0022-5

Schlüsselwörter1-octene conversion, XRD, Co-Mo/MCM-41, BET specific surface area

This content is open access.

Schlüsselwörter
1-octene conversion, XRD, Co-Mo/MCM-41, BET specific surface area