<abstract xmlns="http://www.w3.org/1999/xhtml"><p>The study examined the adsorption of propan-1-ol (1PN) vapour on Sorbonorit 4 (S4) activated carbon in cyclic Electrothermal Temperature Swing Adsorption (ETSA) process. Dynamic adsorption capacity and breakthrough time were determined based on column studies. Thomas model was used to describe experimental breakthrough curves. Adsorption isotherms for 1PN vapour on S4 activated carbon were tested at 293 to 413 K. The experimental data were examined by using three multi-temperature isotherm models: Toth, Sips and hybrid Langmuir-Sips. Results indicate that S4 activated carbon is a heterogeneous adsorbent and the hybrid Langmuir-Sips model provides the best-fit experimental data. The energy requirement for 1PN electrothermal desorption from S4 bed (ca. 170–200 kJ/mol) was about 3 to 3.5 times larger than the isosteric heat of adsorption (56.8 kJ/mol), which was calculated using Toth adsorption isotherm.</p></abstract>

The study examined the adsorption of propan-1-ol (1PN) vapour on Sorbonorit 4 (S4) activated carbon in cyclic Electrothermal Temperature Swing Adsorption (ETSA) process. Dynamic adsorption capacity and breakthrough time were determined based on column studies. Thomas model was used to describe experimental breakthrough curves. Adsorption isotherms for 1PN vapour on S4 activated carbon were tested at 293 to 413 K. The experimental data were examined by using three multi-temperature isotherm models: Toth, Sips and hybrid Langmuir-Sips. Results indicate that S4 activated carbon is a heterogeneous adsorbent and the hybrid Langmuir-Sips model provides the best-fit experimental data. The energy requirement for 1PN electrothermal desorption from S4 bed (ca. 170–200 kJ/mol) was about 3 to 3.5 times larger than the isosteric heat of adsorption (56.8 kJ/mol), which was calculated using Toth adsorption isotherm.

Adsorption of propan-1-ol vapour on Sorbonorit 4 activated carbon – equilibrium and dynamic studies

West Pomeranian University of Technology, Szczecin

Department of Chemical Engineering and Environmental Protection Process

Polish Journal of Chemical Technology

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

The study examined the adsorption of propan-1-ol (1PN) vapour on Sorbonorit 4 (S4) activated carbon in cyclic Electrothermal Temperature Swing Adsorption...

Adsorption of propan-1-ol vapour on Sorbonorit 4 activated carbon – equilibrium and dynamic studies

Online veröffentlicht: 29. Dez. 2017

Seitenbereich: 59 - 64

DOI: https://doi.org/10.1515/pjct-2017-0068

Schlüsselwörter
activated carbon, propan-1-ol, multi-temperature isotherms, electrothermal desorption, breakthrough curve

© 2017 Dorota Downarowicz et al., published by De Gruyter Open

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Adsorption of propan-1-ol vapour on Sorbonorit 4 activated carbon – equilibrium and dynamic studies

Online veröffentlicht: 29. Dez. 2017

Seitenbereich: 59 - 64

DOI: https://doi.org/10.1515/pjct-2017-0068

Schlüsselwörteractivated carbon, propan-1-ol, multi-temperature isotherms, electrothermal desorption, breakthrough curve

© 2017 Dorota Downarowicz et al., published by De Gruyter Open

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Schlüsselwörter
activated carbon, propan-1-ol, multi-temperature isotherms, electrothermal desorption, breakthrough curve