<abstract xml:lang="en" xmlns="http://www.w3.org/1999/xhtml">This paper presents the effect of two dissolved inorganic salts (zinc chloride, ZnCl2 and ammonium chloride, NH4Cl) on the enthalpy of mixing (<italic>H</italic>E) of 2-propanol + acetic acid binary system measured at 303.15 K using an isothermal displacement calorimeter with vapour space. A decreasing trend in the excess enthalpy of mixing values in the presence of ZnCl2 and NH4Cl indicate the endothermic behavior of this system. The Redlich-Kister equation has been used to fit the experimental <italic>H</italic>E data. The deviations from the ideal value and binary parameters were calculated and reported.</abstract>

This paper presents the effect of two dissolved inorganic salts (zinc chloride, ZnCl2 and ammonium chloride, NH4Cl) on the enthalpy of mixing (HE) of 2-propanol + acetic acid binary system measured at 303.15 K using an isothermal displacement calorimeter with vapour space. A decreasing trend in the excess enthalpy of mixing values in the presence of ZnCl2 and NH4Cl indicate the endothermic behavior of this system. The Redlich-Kister equation has been used to fit the experimental HE data. The deviations from the ideal value and binary parameters were calculated and reported.

Salt effect on the enthalpy of mixing of 2-propanol + acetic acid at 303.15 K

Department of Chemistry, Anna University, Tiruchirappalli - Pattukkottai Campus 614 701, India

Department of Chemical Engineering, Alagappa College of Technology, Anna University, Chennai 600 025, India

Department of Chemistry, School of Science, Vellore Institute of Technology University, Vellore 632 014, India

Polish Journal of Chemical Technology

{"article-title":"Salt effect on the enthalpy of mixing of 2-propanol + acetic acid at 303.15 K"}

This paper presents the effect of two dissolved inorganic salts (zinc chloride, ZnCl2 and ammonium chloride, NH4Cl) on the enthalpy of mixing (HE) of...

Salt effect on the enthalpy of mixing of 2-propanol + acetic acid at 303.15 K

Published Online: Jan 08, 2010

Page range: 20 - 23

DOI: https://doi.org/10.2478/v10026-009-0038-6

Keywords
Excess enthalpy, binary system, salt effect, 2-propanal, acetic acid

This content is open access.

Salt effect on the enthalpy of mixing of 2-propanol + acetic acid at 303.15 K

Published Online: Jan 08, 2010

Page range: 20 - 23

DOI: https://doi.org/10.2478/v10026-009-0038-6

KeywordsExcess enthalpy, binary system, salt effect, 2-propanal, acetic acid

This content is open access.

Keywords
Excess enthalpy, binary system, salt effect, 2-propanal, acetic acid