<abstract xmlns="http://www.w3.org/1999/xhtml"><p>In the present work, a new organic second order NLO material: L-isoleucinium p-toluenesulfonate monohydrate (LIPT) is synthesized and reported for the first time. The LIPT is crystallized in a non-centrosymmetric monoclinic space group P2<sub>1</sub>. Structural and hydrogen bond nature of the compound is analyzed using single crystal X-ray diffraction studies. The crystal exhibits very good optical properties such as wide optical transparency in the region of 210 nm to 1100 nm and the ultraviolet wavelength emission (λ = 283 nm). The second harmonic generation efficiency is found to be 1.7 times the standard KDP. Good thermal, mechanical properties and low dielectric constant at high frequency range show that the material may be a potential candidate for optoelectronic applications.</p></abstract>

In the present work, a new organic second order NLO material: L-isoleucinium p-toluenesulfonate monohydrate (LIPT) is synthesized and reported for the first time. The LIPT is crystallized in a non-centrosymmetric monoclinic space group P21. Structural and hydrogen bond nature of the compound is analyzed using single crystal X-ray diffraction studies. The crystal exhibits very good optical properties such as wide optical transparency in the region of 210 nm to 1100 nm and the ultraviolet wavelength emission (λ = 283 nm). The second harmonic generation efficiency is found to be 1.7 times the standard KDP. Good thermal, mechanical properties and low dielectric constant at high frequency range show that the material may be a potential candidate for optoelectronic applications.

Structural, optical, thermal, dielectric and mechanical studies of a new organic NLO material: L-isoleucinium p-toluenesulfonate monohydrate (LIPT)

Department of Physics, University College of Engineering

Materials Science-Poland

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.

In the present work, a new organic second order NLO material: L-isoleucinium p-toluenesulfonate monohydrate (LIPT) is synthesized and reported for the first...

Structural, optical, thermal, dielectric and mechanical studies of a new organic NLO material: L-isoleucinium p-toluenesulfonate monohydrate (LIPT)

Published Online: Aug 02, 2019

Page range: 196 - 205

Received: Mar 20, 2018

Accepted: Mar 11, 2019

DOI: https://doi.org/10.2478/msp-2019-0021

Keywords
optical material, SHG, single crystal XRD, TGA/DTA, UV spectrum

© 2019 M. Suresh et al., published by Sciendo

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.

Structural, optical, thermal, dielectric and mechanical studies of a new organic NLO material: L-isoleucinium p-toluenesulfonate monohydrate (LIPT)

Published Online: Aug 02, 2019

Page range: 196 - 205

Received: Mar 20, 2018

Accepted: Mar 11, 2019

DOI: https://doi.org/10.2478/msp-2019-0021

Keywordsoptical material, SHG, single crystal XRD, TGA/DTA, UV spectrum

© 2019 M. Suresh et al., published by Sciendo

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.

Keywords
optical material, SHG, single crystal XRD, TGA/DTA, UV spectrum