<abstract xmlns="http://www.w3.org/1999/xhtml">Single crystal of glycine hydroflruoride (GHF) was grown from aqueous solution by slow evaporation technique. The structure of the grown crystal was tested and analyzed through X-ray powder diffraction. The functional groups have been identified from the FT-IR spectra. Slabs cut normal to the b-axis from the grown crystal were subjected to incident radiation with a wavelength range of 200 nm to 800 nm to investigate the transmittance and reflectance spectra. Linear optical parameters such as extinction coefficient k, refractive index n and both the real and imaginary parts: ∊real and ∊im of the dielectric permittivity were calculated as functions of the incident photon energy. The dispersion of the refractive index was fitted in terms of Cauchy formula and Wemple-DiDomenico single oscillator model. GHF crystals exhibited indirect optical interband transition and the optical energy gap Eg was determined by using Tauc plot. The indirect band gaps at elevated temperatures were determined and their temperature dependence was estimated. Optical band gap Eg values were found to decrease with an increase in crystal temperature; however, the band tail width exhibited opposite behavior. The nonlinear optical potential was examined by the second harmonic generation (SHG) test.</abstract>

Single crystal of glycine hydroflruoride (GHF) was grown from aqueous solution by slow evaporation technique. The structure of the grown crystal was tested and analyzed through X-ray powder diffraction. The functional groups have been identified from the FT-IR spectra. Slabs cut normal to the b-axis from the grown crystal were subjected to incident radiation with a wavelength range of 200 nm to 800 nm to investigate the transmittance and reflectance spectra. Linear optical parameters such as extinction coefficient k, refractive index n and both the real and imaginary parts: ∊real and ∊im of the dielectric permittivity were calculated as functions of the incident photon energy. The dispersion of the refractive index was fitted in terms of Cauchy formula and Wemple-DiDomenico single oscillator model. GHF crystals exhibited indirect optical interband transition and the optical energy gap Eg was determined by using Tauc plot. The indirect band gaps at elevated temperatures were determined and their temperature dependence was estimated. Optical band gap Eg values were found to decrease with an increase in crystal temperature; however, the band tail width exhibited opposite behavior. The nonlinear optical potential was examined by the second harmonic generation (SHG) test.

Study on some linear and nonlinear optical parameters of glycine hydrofluoride single crystals

Faculty of Science, Department of Physics

Materials Science-Poland

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.

Single crystal of glycine hydroflruoride (GHF) was grown from aqueous solution by slow evaporation technique. The structure of the grown crystal was tested and...

Study on some linear and nonlinear optical parameters of glycine hydrofluoride single crystals

Published Online: Feb 01, 2019

Page range: 685 - 696

Received: Nov 28, 2017

Accepted: May 16, 2018

DOI: https://doi.org/10.2478/msp-2018-0096

Keywords
GHF single crystal, optical energy gap, optical constants, temperature dependence, SHG efficiency

© 2018 A. Abu El-Fadl et al., published by Sciendo

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.

Study on some linear and nonlinear optical parameters of glycine hydrofluoride single crystals

Published Online: Feb 01, 2019

Page range: 685 - 696

Received: Nov 28, 2017

Accepted: May 16, 2018

DOI: https://doi.org/10.2478/msp-2018-0096

KeywordsGHF single crystal, optical energy gap, optical constants, temperature dependence, SHG efficiency

© 2018 A. Abu El-Fadl et al., published by Sciendo

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.

Keywords
GHF single crystal, optical energy gap, optical constants, temperature dependence, SHG efficiency