<abstract xmlns="http://www.w3.org/1999/xhtml">A new and simple micelles-rich restricted access supramolecular solvent-based liquid phase microextraction method (RASUPRASs-LPME) based on the ion-pair complex formation of phosphate (PO43-) ions with ammonium heptamolybdate and malachite green in acidic medium was developed. The phosphate ion concentration after microextraction of the ion-pair complex to the hexagonal aggregates of decanoic acid (DA) was measured with micro-volume UV-Vis spectrophotometer at 625 nm. All analytical parameters which are effective on the method such as acid type and concentration, supramolecular solvent volume, amount of the components forming the complex, sample volume, were optimized. The preconcentration factor (PF), limit of detection (LOD) and limit of quantification (LOQ) for the developed method was found to be 15, 9.6 and 32.1, respectively. The RA-SUPRAs-LPME method was finally applied for the analysis of the phosphate content of different types of water samples.</abstract>

A new and simple micelles-rich restricted access supramolecular solvent-based liquid phase microextraction method (RASUPRASs-LPME) based on the ion-pair complex formation of phosphate (PO43-) ions with ammonium heptamolybdate and malachite green in acidic medium was developed. The phosphate ion concentration after microextraction of the ion-pair complex to the hexagonal aggregates of decanoic acid (DA) was measured with micro-volume UV-Vis spectrophotometer at 625 nm. All analytical parameters which are effective on the method such as acid type and concentration, supramolecular solvent volume, amount of the components forming the complex, sample volume, were optimized. The preconcentration factor (PF), limit of detection (LOD) and limit of quantification (LOQ) for the developed method was found to be 15, 9.6 and 32.1, respectively. The RA-SUPRAs-LPME method was finally applied for the analysis of the phosphate content of different types of water samples.

Micelle-based restricted access ion-pair microextraction of phosphate at trace levels in water samples for separation, preconcentration and determination

The EuroBiotech Journal

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.

A new and simple micelles-rich restricted access supramolecular solvent-based liquid phase microextraction method (RASUPRASs-LPME) based on the ion-pair...

Micelle-based restricted access ion-pair microextraction of phosphate at trace levels in water samples for separation, preconcentration and determination

Article Category: Research Article

Published Online: Apr 30, 2020

Page range: 89 - 96

DOI: https://doi.org/10.2478/ebtj-2020-0010

Keywords
Microextraction, restricted access supramolecular solvent, UV-Vis spectrophotometer, phosphate, ammonium heptamolybdate, malachite green

© 2020 Mustafa Soylak, Haldun Hilmi Gorucu and Erkan Yilmaz, published by Sciendo

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.

Micelle-based restricted access ion-pair microextraction of phosphate at trace levels in water samples for separation, preconcentration and determination

Article Category: Research Article

Published Online: Apr 30, 2020

Page range: 89 - 96

DOI: https://doi.org/10.2478/ebtj-2020-0010

KeywordsMicroextraction, restricted access supramolecular solvent, UV-Vis spectrophotometer, phosphate, ammonium heptamolybdate, malachite green

© 2020 Mustafa Soylak, Haldun Hilmi Gorucu and Erkan Yilmaz, published by Sciendo

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.

Keywords
Microextraction, restricted access supramolecular solvent, UV-Vis spectrophotometer, phosphate, ammonium heptamolybdate, malachite green