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Direct synthesis of dimethyl carbonate and propylene glycol using potassium bicarbonate as catalyst in supercritical CO2


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1. Darensbourg, D.J. (2007). Making Plastics from Carbon Dioxide: Salen Metal Complexes as Catalysts for the Production of Polycarbonates from Epoxides and CO2. Chem. Rev. 107 (6), 2388-2410. DOI:10.1021/cr068363q.10.1021/cr068363qSearch in Google Scholar

2. Jessop, P.G., Ikariya, T. & Noyori, R. (1999). Homogeneous Catalysis in Supercritical Fluids. Chem. Rev. 99 (2), 475-493. DOI: 10.1021/cr970037a.10.1021/cr970037aSearch in Google Scholar

3. Baiker, A. (1999). Supercritical fluids in heterogeneous catalysis. Chem. Rev. 99 (2), 453-474. DOI: 10.1021/cr970090z.10.1021/cr970090zSearch in Google Scholar

4. Darr, J.A. & Poliakoff, M. (1999). New directions in inorganic and metal-organic coordination chemistry in supercritical fluids. Chem. Rev. 99 (2), 495-541. DOI: 10.1021/cr970036i.10.1021/cr970036iSearch in Google Scholar

5. Tundo, P. & Selva, M. (2002). The chemistry of dimethyl carbonate. Acc. Chem. Res. 35 (9), 706-716. DOI: 10.1021/ ar010076f.10.1021/ar010076fSearch in Google Scholar

6. Fukuoka, S., Kawamura, M., Komiya, K., Hachiya, H., Hasegawa, K., Aminaka, M., Okamoto, H., Fukawa, I. & Konno, S. (2003). A novel non-phosgene polycarbonate production process using by-product CO2 as starting material. Green. Chem. 5, 497-507. DOI: 10.1039/B304963A.10.1039/B304963ASearch in Google Scholar

7. King, S.T. (1997). Oxidative Carbonylation of methanol to dimethyl carbonate by solid-state ion-exchanged CuY catalysts. Catal. Today 33, 173-182. DOI: 10.1016/S0920-5861(96)00118-6.10.1016/S0920-5861(96)00118-6Search in Google Scholar

8. Sato, Y., Yamamoto, T. & Souma, Y. (2000). Poly- (pyridine-2,5-diyl)-CuCl2 catalyst for synthesis of dimethyl carbonate by oxidative carbonylation of methanol: catalytic activity and corrosion influence. Catal. Lett. 65, 123-126. DOI: 10.1023/A:1019033725260.10.1023/A:1019033725260Search in Google Scholar

9. Fujita, S.I., Bhanage, B.M., Ikushima, Y. & Arai, M. (2001). Synthesis of dimethyl carbonate from carbon dioxide and methanol in the presence of methyl iodide and base catalysts under mild conditions: effect of reaction conditions and reaction mechanism. Green. Chem. 3 (2), 87-91. DOI: 10.1039/B100363L.10.1039/b100363lSearch in Google Scholar

10. Choi, J.C., Sakakura, T. & Sako, T. (1999). Reaction of dialkyltin methoxide with carbon dioxide relevant to the mechanism of catalytic carbonate synthesis. J. Am. Chem. Soc. 121, 3793-3794. DOI: 10.1021/ja9900499.10.1021/ja9900499Search in Google Scholar

11. Tomishige, K. & Kunimori, K. (2002). Catalytic and direct synthesis of dimethyl carbonate starting from carbon dioxide using CeO2-ZrO2 solid solution heterogeneous catalyst: effect of H2O removal from the reaction system. Appl. Catal. A: Gen. 237, 103-109. DOI: 10.1016/S0926-860X(02)00322-8.10.1016/S0926-860X(02)00322-8Search in Google Scholar

12. Isaacs, N.S., O’Sullivan, B. & Verhaelen, C. (1999) High pressure routes to dimethyl carbonate from supercritical carbon dioxide. Tetrahedron 55, 11949-11956. DOI: 10.1016/ S0040-4020(99)00693-6.10.1016/S0040-4020(99)00693-6Search in Google Scholar

13. Sakakura, T., Choi, J.C., Saito, Y., Masuda, T., Sako, Y., Masuda, T., Sako, T. & Oriyama, T. (1999). Metal-catalyzed dimethyl carbonate synthesis from carbon dioxide and acetals. J. Org. Chem. 64, 4506-4508. DOI: 10.1021/jo990155t.10.1021/jo990155tSearch in Google Scholar

14. Bhanage, B.M., Fujita, S.I., Ikushima, Y., Torii, K. & Arai, M. (2003). Synthesis of dimethyl carbonate and glycols from carbon dioxide, epoxides and methanol using heterogeneous Mg containing smectite catalysts: effect of reaction variables on activity and selectivity performance. Green. Chem. 5, 71-75. DOI: 10.1039/B207750G.10.1039/b207750gSearch in Google Scholar

15. Bhanage, B.M., Fujita, S.I., He, Y.F., Ikushima, Y., Shirai, M., Torii, K. & Arai, M. (2002). Concurrent Synthesis of Dimethyl Carbonate and Ethylene Glycol via Transesterifi- cation of Ethylene Carbonate and Methanol Using Smectite Catalysts Containing Mg and/or Ni. Catal. Lett. 83, 137-141. DOI: 10.1023/A:1021065409888.10.1023/A:1021065409888Search in Google Scholar

16. Sakakura, T. & Kohno, K. (2009). The synthesis of organic carbonates from carbon dioxide. Chem. Comm. 11. 1312-1330. DOI: 10.1039/b819997c.10.1039/b819997cSearch in Google Scholar

17. Bhanage, B.M., Fujita, S.I., Ikushima, Y. & Arai, M. (2001). Synthesis of dimethyl carbonate and glycols from carbon dioxide, epoxides, and methanol using heterogeneous basic metal oxide catalysts with high activity and selectivity. Appl. Catal. A: Gen. 219 (1-2), 259-266. DOI: 10.1016/S0926-860X(01)00698-6.10.1016/S0926-860X(01)00698-6Search in Google Scholar

18. Chang, Y.H., Jiang, T., Han, B.X., Liu, Z.M., Wu, W.Z., Gao, L., Li, J.C., Gao, H.X., Zhao, G.Y. & Huang, J. (2004). One-pot synthesis of dimethyl carbonate and glycols from supercritical CO2, ethylene oxide or propylene oxide, and methanol. Appl. Catal. A: Gen. 263 (2), 179-186. DOI: 10.1016/j.apcata.2003.12.012.10.1016/j.apcata.2003.12.012Search in Google Scholar

19. Fan, B., Qu, B., Chen, Q.C., Wen, Y.C., Cai, L. & Zhang, R. (2011). An improved one-pot synthesis of dimethyl carbonate from propylene oxide, CO2 and methanol. J. Chem. Res. 35, 654-656. DOI: 10.3184/174751911X13192908398731. 10.3184/174751911X13192908398731Search in Google Scholar

eISSN:
1899-4741
Language:
English
Publication timeframe:
4 times per year
Journal Subjects:
Industrial Chemistry, Biotechnology, Chemical Engineering, Process Engineering