<abstract xmlns="http://www.w3.org/1999/xhtml"> Multiferroic 0.5BiFeO3-0.5Pb(Fe0.5Ta0.5)O3 solid solution is a material that exhibits ferroelectric and antiferromagnetic orderings in ambient temperature. The solid solution was obtained as a result of a conventional reaction in a solid state. The obtained material is a dense, fine-grained sinter whose surface was observed by scanning electron microscopy (SEM) and stoichiometry was confirmed by energy dispersive X-ray spectroscopic (EDS) analysis. According to the X-ray powder diffraction (XRD) measurements, the main phase is R3c space group with admixture of Pm-3m regular phase. Small contribution of pyrochlore-like phase was also observed. Mössbauer spectroscopy suggested random distribution of Fe3+/Ta5+ cations in the B sites of ABO3 compound. Reduction of the magnetic hyperfine field with an increase in the substitution of Ta5+ in Fe3+ neighbourhood was also observed.</abstract>

Multiferroic 0.5BiFeO3-0.5Pb(Fe0.5Ta0.5)O3 solid solution is a material that exhibits ferroelectric and antiferromagnetic orderings in ambient temperature. The solid solution was obtained as a result of a conventional reaction in a solid state. The obtained material is a dense, fine-grained sinter whose surface was observed by scanning electron microscopy (SEM) and stoichiometry was confirmed by energy dispersive X-ray spectroscopic (EDS) analysis. According to the X-ray powder diffraction (XRD) measurements, the main phase is R3c space group with admixture of Pm-3m regular phase. Small contribution of pyrochlore-like phase was also observed. Mössbauer spectroscopy suggested random distribution of Fe3+/Ta5+ cations in the B sites of ABO3 compound. Reduction of the magnetic hyperfine field with an increase in the substitution of Ta5+ in Fe3+ neighbourhood was also observed.

Crystal structure and Mössbauer effect in multiferroic 0.5BiFeO3-0.5Pb(Fe0.5Ta0.5)O3 solid solution

Nukleonika

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Crystal structure and Mössbauer effect in multiferroic 0.5BiFeO-0.5Pb(FeTa)O solid solution

Multiferroic 0.5BiFeO3-0.5Pb(Fe0.5Ta0.5)O3 solid solution is a material that exhibits ferroelectric and antiferromagnetic orderings in ambient temperature. The...

Crystal structure and Mössbauer effect in multiferroic 0.5BiFeO₃-0.5Pb(Fe_0.5Ta_0.5)O₃ solid solution

Published Online: Jun 09, 2017

Page range: 177 - 181

Received: Jun 26, 2016

Accepted: Jun 26, 2016

DOI: https://doi.org/10.1515/nuka-2017-0027

Keywords
BiFeO3, crystal structure, hyperfine interactions, multiferroics, solid solution

© by Agata Stoch

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.

Crystal structure and Mössbauer effect in multiferroic 0.5BiFeO3-0.5Pb(Fe0.5Ta0.5)O3 solid solution

Published Online: Jun 09, 2017

Page range: 177 - 181

Received: Jun 26, 2016

Accepted: Jun 26, 2016

DOI: https://doi.org/10.1515/nuka-2017-0027

KeywordsBiFeO3, crystal structure, hyperfine interactions, multiferroics, solid solution

© by Agata Stoch

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.

Crystal structure and Mössbauer effect in multiferroic 0.5BiFeO₃-0.5Pb(Fe_0.5Ta_0.5)O₃ solid solution

Keywords
BiFeO3, crystal structure, hyperfine interactions, multiferroics, solid solution