<abstract xmlns="http://www.w3.org/1999/xhtml">In this work the synthesis of hercynite from Fe2O3 and Al2O3 powders was carried out by arc-melting method under the protective argon atmosphere. The obtained material was characterized with the use of powder X-ray diffractometry (XRD) and Mössbauer spectroscopy (MS). A Mössbauer effect in hercynite obtained by the arc-melting method indicated the cations distribution in the spinel structure among the tetrahedral and octahedral interstices. The presence of Fe2+ ions was detected in both tetrahedral and octahedral sites while Fe3+ ions occupied only the octahedral interstices. The approximate formula of the obtained iron-aluminate spinel was as follows (Fe2+0.77Al3+0.23) (Fe3+0.07Fe2+0.05Al0.88)2O4.</abstract>

In this work the synthesis of hercynite from Fe2O3 and Al2O3 powders was carried out by arc-melting method under the protective argon atmosphere. The obtained material was characterized with the use of powder X-ray diffractometry (XRD) and Mössbauer spectroscopy (MS). A Mössbauer effect in hercynite obtained by the arc-melting method indicated the cations distribution in the spinel structure among the tetrahedral and octahedral interstices. The presence of Fe2+ ions was detected in both tetrahedral and octahedral sites while Fe3+ ions occupied only the octahedral interstices. The approximate formula of the obtained iron-aluminate spinel was as follows (Fe2+0.77Al3+0.23) (Fe3+0.07Fe2+0.05Al0.88)2O4.

Crystal structure and Mössbauer study of FeAl2O4

Department of Ceramics and Refractories, Faculty of Materials Science and Ceramics, AGH – University of Science and Technology, 30 Mickiewicza Ave., 30-059 Kraków, Poland

Mössbauer Spectroscopy Division, Institute of Physics, Pedagogical University, 2 Podchorążych Str., 30-084 Kraków, Poland

Nukleonika

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Crystal structure and Mössbauer study of FeAlO

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In this work the synthesis of hercynite from Fe2O3 and Al2O3 powders was carried out by arc-melting method under the protective argon atmosphere. The obtained...

Crystal structure and Mössbauer study of FeAl₂O₄

Published Online: Mar 12, 2015

Page range: 47 - 49

Received: Jun 18, 2014

Accepted: Nov 02, 2014

DOI: https://doi.org/10.1515/nuka-2015-0012

Keywords
FeAlO, hercynite, Mössbauer spectroscopy, spinel

© Ilona Jastrzębska, Jacek Szczerba, Paweł Stoch, Artur Błachowski, Krzysztof Ruebenbauer, Ryszard Prorok, Edyta Śnieżek

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Crystal structure and Mössbauer study of FeAl2O4

Published Online: Mar 12, 2015

Page range: 47 - 49

Received: Jun 18, 2014

Accepted: Nov 02, 2014

DOI: https://doi.org/10.1515/nuka-2015-0012

KeywordsFeAlO, hercynite, Mössbauer spectroscopy, spinel

© Ilona Jastrzębska, Jacek Szczerba, Paweł Stoch, Artur Błachowski, Krzysztof Ruebenbauer, Ryszard Prorok, Edyta Śnieżek

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Crystal structure and Mössbauer study of FeAl₂O₄

Keywords
FeAlO, hercynite, Mössbauer spectroscopy, spinel