<abstract xmlns="http://www.w3.org/1999/xhtml"> Mg substituted cobalt ferrite spinel powder samples with the general formula MgxCO1-xFe2O4(x = 0 to 0.25) were synthesized chemically through sol-gel method and annealed at 1100 °C for 2 h. They were initially screened for the structural and morphological properties by X-ray diffraction and field emission scanning electron microscopy, respectively. Vibrational properties of the samples were studied by Raman and infrared spectroscopies. X-ray diffraction confirmed the formation of single pure or near-pure phase with cubic spinel structure for all the samples with expected occupancy values. The field emission scanning electron microscopy revealed a decrease in the particle size with an increase in Mg concentration. Both structural and magnetic properties of the samples were characterized using Mössbauer spectroscopy while the magnetic properties were studied using vibrating sample magnetometry. The changes in magnetic moment of ions, their coupling with neighboring ions and cation exchange interactions were confirmed from the Mössbauer spectroscopy analysis. Saturation magnetization and coercivity values can be explained based on the Slater-Pauling curve. The magnetometry results showed a decrease in saturation magnetization of the samples with increase in Mg concentration</abstract>

Mg substituted cobalt ferrite spinel powder samples with the general formula MgxCO1-xFe2O4(x = 0 to 0.25) were synthesized chemically through sol-gel method and annealed at 1100 °C for 2 h. They were initially screened for the structural and morphological properties by X-ray diffraction and field emission scanning electron microscopy, respectively. Vibrational properties of the samples were studied by Raman and infrared spectroscopies. X-ray diffraction confirmed the formation of single pure or near-pure phase with cubic spinel structure for all the samples with expected occupancy values. The field emission scanning electron microscopy revealed a decrease in the particle size with an increase in Mg concentration. Both structural and magnetic properties of the samples were characterized using Mössbauer spectroscopy while the magnetic properties were studied using vibrating sample magnetometry. The changes in magnetic moment of ions, their coupling with neighboring ions and cation exchange interactions were confirmed from the Mössbauer spectroscopy analysis. Saturation magnetization and coercivity values can be explained based on the Slater-Pauling curve. The magnetometry results showed a decrease in saturation magnetization of the samples with increase in Mg concentration

Correlation between Structural, Magnetic and Spectroscopic Properties of Mg Substituted CoFe2O4

Materials Science-Poland

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Correlation between Structural, Magnetic and Spectroscopic Properties of Mg Substituted CoFeO

Mg substituted cobalt ferrite spinel powder samples with the general formula MgxCO1-xFe2O4(x = 0 to 0.25) were synthesized chemically through sol-gel method...

Correlation between Structural, Magnetic and Spectroscopic Properties of Mg Substituted CoFe₂O₄

Published Online: Jun 25, 2018

Page range: 310 - 319

Received: Jun 05, 2017

Accepted: Mar 28, 2018

DOI: https://doi.org/10.1515/msp-2018-0043

Keywords
Mg substituted cobalt ferrite, sol-gel method, Rietveld refinement, vibrational properties, spectroscopic techniques

© 2018 Gnana Praveena Nethala et al., published by Sciendo

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.

Correlation between Structural, Magnetic and Spectroscopic Properties of Mg Substituted CoFe2O4

Published Online: Jun 25, 2018

Page range: 310 - 319

Received: Jun 05, 2017

Accepted: Mar 28, 2018

DOI: https://doi.org/10.1515/msp-2018-0043

KeywordsMg substituted cobalt ferrite, sol-gel method, Rietveld refinement, vibrational properties, spectroscopic techniques

© 2018 Gnana Praveena Nethala et al., published by Sciendo

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.

Correlation between Structural, Magnetic and Spectroscopic Properties of Mg Substituted CoFe₂O₄

Keywords
Mg substituted cobalt ferrite, sol-gel method, Rietveld refinement, vibrational properties, spectroscopic techniques