The Baltic Shield is a part of the East European Kraton (EEC), revealing to the north-east of St. Petersburg, appearing in the region of Karelia, Finland, Sweden and the Kola Peninsula, disappearing in the north-west at Caledonian massif of the Scandinavian Mountains, located in Norway. The rocks located within the Baltic Shield are divided into several specific blocks. They are: Kola and Belamorian, Karelian and Svekofenian and Scandinavian or Sveko-Norvegian Blocks.
The oldest blocks in the Baltic Shield are Kola and Belamoryian. They are exposed mainly in the area of the Kola Peninsula and Karelia. In some locations these rocks reach the age of about 3.7 Ga. They have a mosaic structure composed of migmatised granites with numerous intrusions and series of greenschists belts of an age between 3 and 2.4 Ga (Mitrofanov, 2000; Bayanova, 2004; Bayanova
The Monchegorsk Massif is located in the central part of the Kola peninsula, in a close vicinity of Khibina alka-line rocks. These intrusions constitute the extension of the Imandra–Warzuga belt which is located on the sepa-rating zone of the Kola and Belamoryan blocks. In Monchegorsk area there are numerous basic and ultraba-sic intrusions that were relatively early investigated by the Russian geologists in the 1920s (Pozhylienko
In this study we consider different sulfide mineralization stages distinguished by petrological observations and by the sulfur isotope analysis of previously dated (Sm-Nd) sulfides.
The samples of rocks were taken during a field trip in cooperation with Russian colleagues in the Monchegorsk Region. The samples of selected sulfide minerals were taken from Russian Academy of Science in Apatity (Russia). The sulfides were analyzed using an optical polarizing microscope Leica DM2500P and a scanning electron microscope Hitachi SU6600 with Energy Dispersive electron (EDS) which are installed in the Department of Geology and Lithosphere Protection at the Maria Curie–Sklodowska University (UMCS) in Lublin, Poland. The stable isotope analysis, δ34S, were made at the Institute of Physics at UMCS, Lublin, on a dual inlet and triple collector mass-spectrometer, using SO2 as the analyzed gas. The sulfide mineral specimens were quantitatively converted to SO2 in a vacuum line by their oxidation with analytical grade CuO reagent at temperatures between 800 and 900°C. Along with the analyzed specimens, an aliquot of 20 mg of the IAEA-S1 standard (Ag2S) was converted to SO2 and analyzed using the mass spectrometer in order to normalize the obtained δ34S values to the Vienna Canyon Diablo Troilite (VCDT) scale. Selected samples were subjected to ICP-MS analysis (model ELAN DRC II, Perkin Elmer LSX-500, of CETAC) at the Soil Science and soil Protection Department at the UMCS. These analyses are necessary for the comparison of the microanalysis results in the studied sulfide minerals samples. They are also important to determinate the chemical composition and metallic additions in the analyzed sulfides.
The Monchegorsk Massif consists of basic and ultra-basic intrusions. These rocks are metamorphosed to a different degree. Relatively, the least metamorphosed are gabbroides occurring in the Monchegorsk region. A little further, on south-west there are rocks metamorphosed mainly in the amphibolite facies. Due to the nature of these intrusions, peridotites represent the most important type of rocks, accompanied by massive ore and the youngest breccias.
This peridotites have grey color with macroscopically visible pyroxenes and accompanying olivines with the addition of feldspars. It has a coarsely crystalline structure and a dense, disorderly texture. In the thin section there are visible clinopyroxenes, represented by augite and diopside, next to which there are amphiboles (common hornblende with a distinctive greenish pleochroism colors). These minerals are accompanied by chromite, olivines and sometimes basic plagioclase, mainly labradore. In addition to these minerals one can also encounter numerous ore minerals represented by titanomagnetite, pyrite and pentlandite (
Within these rocks they are associated massive sulfide ore deposits, mainly composed of pyrite and pentlandite, chalcopyrite and breccias containing all the above men-tioned types of rocks. These breccias are composed of crushed rocks of peridotites which are cemented by quartz and sulfides. The microscopic observation indi-cates sulfides such as pyrite, chalcopyrite and secondary altered gabbroids by serpentinization and saussuritization processes (
Studied sulfide minerals have shown that they are mainly crystals of pyrite and chalcopyrite accompanied grains of pentlandite and also magnetite, titanomagnetite and ilmenite. Especially in the massive ore samples of titanomagnetite, magnetite and ilmenite form enclaves, appearing in the form of aggregates in-between sulfides. In the close proximity of these minerals, pyrrohotite, bornite, cupropentlandite form characteristic lamellar adhesions and demix near the contact of iron minerals (visible in the microscopic image on
Microscopic observation of ore minerals indicate the existence of several generations. The oldest, associated with primary magma mineralization is represented by the sulfides of nickel, accompanied by iron and titanium oxides. These minerals are visible both in peridotites as well as in the massive ores, where particularly oxides are surrounded by copper and iron sulfides, showing secondary structures (
The microprobe analyses of sulfides showed that the iron oxide is accompanied by small quantities of V2O5 and manganese oxides (
The gabbronorites from the Pentlanditovaya Ushchelie deposits in the lowermost part of Monchegorsk pluton yielded 2489 ± 49 Ma (Sm-Nd) and 2501 ± 5.6 Ma (U-Pb), respectively (Huber
Results of stable sulfur isotope analysis of separated sulfide minerals of the three ore samples shows some variability (
The results of the δ 34S for the Monchegorsk sulfide minerals samples.
Sample | δ34S VCDT (‰) |
---|---|
01 pyrite with admixtures | 5.74 |
01 pentlandite | 0.92 |
02 pyrite | 1.36 |
02 chalkopyrite | 2.52 |
02 chalkopyrite | 0.58 |
02 pentlandite | 2.18 |
03 pentlandite | 0.04 |
03 pentlandite | 1.04 |
03 pentlandite | 3.34 |
03 pyrite | 1.64 |
03 pyrite | 0.75 |
The examined three types of rocks from Monchegorsk contain several generations of sulfide minerals. The oldest of them are associated with magmatic rocks. Next generation was probably formed during metamorphism of these rocks, which has been identified by Serov
These results closely correlate with the change in the distribution of sulfur isotopes previously encountered in northern Canada and Greenland by Hattori
Inasmuch as the oldest sulfides are as old as 2.5 Ga, as mentioned above, therefore our data presented in
The analyzed sulfide minerals from Monchegorsk massif rocks indicate high variability of isotopic composition resulting from the coexistence of several generations of sulfides. These generations proceeded over a long span of time, from 2.5 to
Generally, the results of analyzes demonstrate the following characteristics of geological phenomena: multiple ultrabasic magma injection in the cooling rock which contributes to a certain oscillation of sulfur isotopes of primary sulfide phases, multi-stage mineralization (magmatic, magmatic secondary, hydrothermal, epigenetic) which is associated with metamorphism of sulfide ores and numerous regional tectonic processes.