<abstract xmlns="http://www.w3.org/1999/xhtml">By using crystal field theory, the spin-Hamiltonian parameters [zero-field splitting D, the giromagnetic factors g (<italic>g</italic>|| and <italic>g</italic>⊥) and the first excited state splitting <italic>δ</italic>(2<italic>E</italic>)] for the CrLi3+ doped in LiNbO3 have been calculated from the higher-order perturbation formulas. The method used is based on the two-spin-orbit coupling parameter model, in a cluster approach. The g parameters were also calculated as a second derivative of the energy, method implemented into ORCA computer program. The results were discussed and good agreement with experimental data was demonstrated.</abstract>

By using crystal field theory, the spin-Hamiltonian parameters [zero-field splitting D, the giromagnetic factors g (g|| and g⊥) and the first excited state splitting δ(2E)] for the CrLi3+ doped in LiNbO3 have been calculated from the higher-order perturbation formulas. The method used is based on the two-spin-orbit coupling parameter model, in a cluster approach. The g parameters were also calculated as a second derivative of the energy, method implemented into ORCA computer program. The results were discussed and good agreement with experimental data was demonstrated.

Spin-Hamiltonian Parameters For CrLi3+ Doped In LiNbO3

Department of Physics, West University of Timisoara, Bd. V. Parvan 4, Timisoara 300223, Romania

Academy of Romanian Scietists, Splaiul Independentei 54, Bucharest 050094, Romania

Institute of Physics, University of Tartu, Riia 142, Tartu 51014, Estonia

Annals of West University of Timisoara - Physics

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Spin-Hamiltonian Parameters For Cr Doped In LiNbO

By using crystal field theory, the spin-Hamiltonian parameters [zero-field splitting D, the giromagnetic factors g (g|| and g⊥) and the first excited state...

Spin-Hamiltonian Parameters For Cr_Li³⁺ Doped In LiNbO₃

Published Online: Oct 05, 2015

Page range: 1 - 8

Received: Sep 07, 2011

Accepted: Nov 19, 2011

DOI: https://doi.org/10.1515/awutp-2015-0001

Keywords
Cr, spin-Hamiltonian parameters, two-spin-orbit interaction model

© N.M. Avram et al.

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Spin-Hamiltonian Parameters For CrLi3+ Doped In LiNbO3

Published Online: Oct 05, 2015

Page range: 1 - 8

Received: Sep 07, 2011

Accepted: Nov 19, 2011

DOI: https://doi.org/10.1515/awutp-2015-0001

KeywordsCr, spin-Hamiltonian parameters, two-spin-orbit interaction model

© N.M. Avram et al.

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Spin-Hamiltonian Parameters For Cr_Li³⁺ Doped In LiNbO₃

Keywords
Cr, spin-Hamiltonian parameters, two-spin-orbit interaction model