<abstract xmlns="http://www.w3.org/1999/xhtml"><p>The SEM and EDS study results of coatings obtained on titanium by Plasma Electrolytic Oxidation (PEO) in the electrolytes containing of 600 g copper nitrate in 1 liter of concentrated phosphoric acid at 450 V for 1 and 3 minutes, are presented. The obtained coatings are porous and consist mainly of phosphorus within titanium and copper. It was found that the time of PEO oxidation has impact on the chemical composition of the coatings. The longer time of PEO treatment, the higher amount of copper inside coating. The PEO oxidation of titanium for 1 minute has resulted in the creation of coating, on which 3 phases where found, which contained up to 13.4 wt% (9 at%) of copper inside the phosphate structure. In case of 1 minute PEO treatment of titanium, the 2 phases were found, which contained up to 13 wt% (8 at%) of copper inside the phosphate structure. The copper-to-phosphorus ratios after 1 minute processing belong to the range from 0.28 by wt% (0.14 by at%) to 0.47 by wt% (0.23 by at%), while after 3 minutes the same ratios belong to the range from 0.27 by wt% (0.13 by at%) to 0.35 by wt% (0.17 by at%). In summary, it should be stated that the higher amounts of phosphorus and copper were recorded on titanium after PEO oxidation for 3 minutes than these after 1 minute.</p></abstract>

The SEM and EDS study results of coatings obtained on titanium by Plasma Electrolytic Oxidation (PEO) in the electrolytes containing of 600 g copper nitrate in 1 liter of concentrated phosphoric acid at 450 V for 1 and 3 minutes, are presented. The obtained coatings are porous and consist mainly of phosphorus within titanium and copper. It was found that the time of PEO oxidation has impact on the chemical composition of the coatings. The longer time of PEO treatment, the higher amount of copper inside coating. The PEO oxidation of titanium for 1 minute has resulted in the creation of coating, on which 3 phases where found, which contained up to 13.4 wt% (9 at%) of copper inside the phosphate structure. In case of 1 minute PEO treatment of titanium, the 2 phases were found, which contained up to 13 wt% (8 at%) of copper inside the phosphate structure. The copper-to-phosphorus ratios after 1 minute processing belong to the range from 0.28 by wt% (0.14 by at%) to 0.47 by wt% (0.23 by at%), while after 3 minutes the same ratios belong to the range from 0.27 by wt% (0.13 by at%) to 0.35 by wt% (0.17 by at%). In summary, it should be stated that the higher amounts of phosphorus and copper were recorded on titanium after PEO oxidation for 3 minutes than these after 1 minute.

Energy-Dispersive X-Ray Spectroscopy Mapping of Porous Coatings Obtained on Titanium by Plasma Electrolytic Oxidation in a Solution Containing Concentrated Phosphoric Acid with Copper Nitrate

Koszalin University of Technology, Faculty of Mechanical Engineering, Department of Engineering and Informatics Systems, Division of Bioengineering and Surface Electrochemistry, Racławicka 15-17, 75-620 Koszalin,

Hochschule Wismar-University of Applied Sciences Technology, Business and Design, Faculty of Engineering, DE 23966 Wismar,

Advances in Materials Science

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

The SEM and EDS study results of coatings obtained on titanium by Plasma Electrolytic Oxidation (PEO) in the electrolytes containing of 600 g copper nitrate in...

Energy-Dispersive X-Ray Spectroscopy Mapping of Porous Coatings Obtained on Titanium by Plasma Electrolytic Oxidation in a Solution Containing Concentrated Phosphoric Acid with Copper Nitrate

Published Online: Oct 18, 2016

Page range: 15 - 25

DOI: https://doi.org/10.1515/adms-2016-0013

Keywords
Plasma Electrolytic Oxidation (PEO), Micro Arc Oxidation (MAO), SEM, Titanium, HPO, Cu(NO)

© 2016 K. Rokosz et al., published by De Gruyter Open

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Energy-Dispersive X-Ray Spectroscopy Mapping of Porous Coatings Obtained on Titanium by Plasma Electrolytic Oxidation in a Solution Containing Concentrated Phosphoric Acid with Copper Nitrate

Published Online: Oct 18, 2016

Page range: 15 - 25

DOI: https://doi.org/10.1515/adms-2016-0013

KeywordsPlasma Electrolytic Oxidation (PEO), Micro Arc Oxidation (MAO), SEM, Titanium, HPO, Cu(NO)

© 2016 K. Rokosz et al., published by De Gruyter Open

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Keywords
Plasma Electrolytic Oxidation (PEO), Micro Arc Oxidation (MAO), SEM, Titanium, HPO, Cu(NO)