The electro-synthesis of poly(aniline-co-para–aminophenol) on graphite electrode was examined using cyclic voltammetry (CV) over the potential window of −0.2 V to 1 V in phosphoric acid medium, which was comprised of potassium chloride and para–Toluene sulfonic acid (pTSA) as electrolyte support. Fourier transform infrared (FTIR) spectroscopy was employed to identify the electro-synthesized copolymer while impedance techniques were used to determine charge transfer resistance (Rct) in modified and unmodified electrodes. After this, the electro-catalytic effect of the modified electrode on ascorbic acid was examined using differential pulse voltammetry (DPV) and a very strong response was observed. A negative shift of about 0.33 V was found in the peak anodic potentials for ascorbic acid. Measurement using DPV indicated a proper response by the electrode to a wide range of ascorbic acid concentrations, from 0.0001 to 0.0004 M. The peak anodic currents for increased concentrations showed a proper linear range.
