A novel biobased polyester plasticizer prepared from palm oil and its plasticizing effect on poly (vinyl chloride)

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In this study, palm oil was the first time to convert into a novel polyester plasticizer for polyvinyl chloride (PVC). In the first stage, palm oil was converted into palm oil monoglyceride (POM) by alcoholysis with glycerol. Next, a novel palm oil monoglycerides based polyester plasticizer (POMP) was synthesized from POM and maleic anhydride through esterification and condensation reaction. The structure of POMP was characterized with FTIR, 1H NMR and GPC. Then PVC blends were prepared using POMP as a plasticizer, melting behavior, thermal property, compatibility, mechanical properties and mechanism of plasticization of PVC blends were systematically studied. Melting behavior indicated that POMP could decrease the torque and the melt viscosity of PVC blends that was conducive to process. With the content of POMP increasing from 5 g to 15 g in PVC blends, the plasticized PVC blends demonstrated better compatibility, the degradation temperature (Td) increased from 252.6°C to 257.0°C, the glass transition temperature (Tg) decreased from 55°C to 49.5°C. Plasticization was put into effect by interaction of the electron cloud between the PVC chain and POMP molecule. This study may lead to the development of new type of PVC plasticizer based on vegetable oil.

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  • 1. Bozell J.J. Moens L. Elliott D.C. Wang Y. Neuenscwander G.G. Fitzpatrick S.W. Bilski R.J. & Jarnefeld J.L. (2000). Production of levulinic acid and use as a platform chemical for derived products. Resour. Conserv. Recy. 28 227–239. DOI: S0921-3449(99)00047-6.

  • 2. Bozell J.J. (2008). Feedstocks for the Future – Biorefinery Production of Chemicals from Renewable. Carbon Clean: Soil Air Water 36(8) 641–647. DOI:10.1002/clen.200800100.

  • 3. Williams C.K. & Hillmyer M.A. (2008). Polymers from Renewable Resources: A Perspective for a Special Issue of Polymer Reviews. Polym. Rev. 48 1–10. DOI: 10.1080/15583720701834133.

  • 4. Ronda J.C. Lligadas G. Galià M. & Cádiz V. (2011). Vegetable oils as platform chemicals for polymer synthesis. Eur. J. Lipid Sci. Technol. 113 46–58. DOI: 10.1002/ejlt.201000103.

  • 5. Edem D.O. (2002). Palm oil: Biochemical physiological nutritional hematological and toxicological aspects: A review. Plant Foods Hum. Nutr. 57 319–341.

  • 6. Zhang L.Q. Zhang M. Hu L.H. & Zhou Y.H. (2014). Synthesis of rigid polyurethane foams with castor oil-based flame retardant polyols. Ind. Crop Prod. 52 380–388. http://dx.doi.org/10.1016/j.indcrop.2013.10.043

  • 7. Liu C.G. Li J. Lei W. & Zhou Y.H. (2014). Development of biobased unsaturated polyester resin containing highly functionalized castor oil. Ind. Crop Prod. 52 329–337. http://dx.doi.org/10.1016/j.indcrop.2013.11.010

  • 8. Saeki Y. & Emura T. (2002). Technical progresses for PVC production. Prog. Polym. Sci. 27 2055–2131. http://www.elsevier.com/locate/ppolysci.

  • 9. Liang G.G. Cook W.D. Tcharkhtchi A. Sautereau H. (2011). Epoxy as a reactive plasticizer for improving polycarbonate processibility. Eur. Polym. J. 47 1578–1588. DOI: 10.1016/j.eurpolymj.2011.05.005.

  • 10. Xu Q. Yin X. Wang M. Wang H. Zhang N. & Shen. (2010). Analysis of phthalate migration from plastic containers to packaged cooking oil and mineral water. J. Agr. Food Chem. 58 11311–11317. DOI: 10.1021/jf102821h.

  • 11. Ioannis S. Arvanitoyannis K. & Kotsanopoulos V. (2012). Smoking of fish and feafood: History Methods and Effects on Physical Nutritional and Microbiological Properties. Food Bioprocess Tech. 5 831–853. DOI: 10.1007/s11947-011-0690-8.

  • 12. Lardjane N. Belhaneche-Bensemra N. & Massardier V. (2013). Migration of new bio-based additives from rigid and plasticized PVC stabilized with epoxidized sunflower oil in soil. J. Polym. Res. 20 209–219. DOI: 10.1007/s10965-013-0209-2.

  • 13. Sander M.M. Nicolau A. Guzatto R. & Samios D. (2012). Plasticiser effect of oleic acid polyester on polyethylene and polypropylene. Polym. Test. 31 1077–1082. http://dx.doi.org/10.1016/j.polymertesting.2012.08.006

  • 14. Silva M.A.D. Vieira M.G.A. Maçumoto A.C.G. & Beppu M.M. (2011). Polyvinylchloride (PVC) and natural rubber films plasticized with a natural polymeric plasticizer obtained through polyesterification of rice fatty acid. Polym. Test 30 478–484. DOI: 10.1016/j.polymertesting.2011.03.008.

  • 15. Bueno-Ferrer C. Garrigós M.C. & Jiménez A. (2012). Characterization and thermal stability of poly(vinyl chloride) plasticized with epoxidized soybean oil for food packaging. Polymer Degrad. Stab. 95 2207–2212. DOI: 10.1016/j.polymdegradstab.2010.01.027.

  • 16. Karmalm P. Hjertberg T. Jansson A. & Dahl R. (2009). Thermal stability of poly(vinyl chloride) with epoxidised soybean oil as primary. plasticizer Polymer Degrad. Stab. 94 2275–2281. DOI: 10.1016/j.polymdegradstab.2009.07.019.

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