Using of wooden sawdust for copper removal from waters

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Abstract

The heavy metal removal from wastewater is very important due to their persistent character in aquatic environment. The use of wooden sawdust is emerging as a potential alternative to the existing conventional technologies for the removal of metal ions from aqueous solutions. The aim of this work is to study the Cu(II) removal of from water by unconventional waste products including the wooden sawdust of poplar, cherry, spruce and hornbeam. The FT-IR spectra of the studied wooden sawdust confirmed the presence of functional groups that have potential for heavy metal binding. The highest efficiency of Cu(II) removal was observed for poplar wooden sawdust at static (86 %) and dynamic (88 %) adsorption experiments. Data obtained by neutron activation analysis revealed that ion exchange is also a mechanism of metal removal by the selected wooden sawdust.

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  • Ahluwalia SS Goyal D (2005) Removal of heavy metals by waste tea leaves from aqueous solution. Eng. Life Sci. 5: 158-162.

  • Ahmad A Rafatullah M Sulaima O Ibrahim MH Chii YY Siddique BM (2009) Removal of Cu(II) and Pb(II) ions from aqueous solutions by adsorption on sawdust of Meranti wood. Desalination 247: 636-646.

  • Ahmaruzzaman M (2011) Industrial wastes as low-cost potential adsorbents for the treatment of wastewater laden with heavy metals. Adv. Colloid Interface Sci. 166: 36-59.

  • Asadi F Shariatmadari H Mirghaffari N (2008) Modification of rice hull and sawdust sorptive characteristics for remove heavy metals from synthetic solutions and wastewater. J. Hazard. Mater. 154: 451-458.

  • Babel S Kurniawan TA (2003) Low-cost adsorbents for heavy metals uptake from contaminated water: A review. J. Hazard. Mater. 97: 219-243.

  • Bailey SE Olin T J Bricka RM Adrian DD (1999) A review of potentially low-cost sorbents for heavy metals. Water Res. 33: 2469-2479.

  • Celik A Demirbaş A (2005) Removal of heavy metal ions from aqueous solutions via adsorption onto modified lignin from pulping wastes. Energ. Source. 27: 1167-1177.

  • Crini G (2006) Non-conventional low-cost adsorbents for dye removal: A review. Bioresour. Technol. 97: 1061-1085.

  • Demcak S Balintova M Demcakova M (2017a) Study of heavy metals removal from model solutions by wooden materials. In IOP Conference Series: Earth and Environmental Science vol. 92 IOP Publishing p. 1-5.

  • Demcak S Balintova M Hurakova M Frontasyeva MV Zinicovscaia I Yushin N (2017b) Utilization of poplar wood sawdust for heavy metals removal from model solutions. Nova Biotechnol. Chim. 16: 26-31.

  • Frontasyeva MV (2011) Neutron activation analysis in the life sciences. Phys. Part. Nucl. 42: 332-378.

  • Gardea-Torresdey JL Becker-Hapak MK Hosea JM Darnall DW (1990) Effect of chemical modification of algal carboxyl groups on metal ion binding. Environ. Sci. Technol. 24: 1372-1378.

  • Gardea-Torresdey JL Gonzalez JH Tiemann KJ Rodriguez O Gamez G (1998) Phytofiltration of hazardous cadmium chromium lead and zinc ions by biomass of Medicago sativa (Alfalfa). J. Hazard. Mater. 57: 29-39.

  • Ghosh S Dhole K Tripathy MK Kumar R Sharma RS (2015) FTIR spectroscopy in the characterization of the mixture of nuclear grade cation and anion exchange resins. J. Radioanal. Nucl. Chem. 304: 917-923.

  • Holub M Balintova M Demcak S Pavlikova P (2016) Application of waste materials as potential biosorbents for Cu (II) and Zn (II) removal. Chem. Technol. 67: 40-45.

  • Holub M Balintova M Pavlikova P (2013) Removal of metal ions from acidic solutions using peat – a low cost sorbent. In Proceedings of the 13th International Conference of Environmental Science and Technology Athens Greece September 5-7 p. 1-6.

  • Imamoglu M Tekir O (2008) Removal of copper (II) and lead (II) ions from aqueous solutions by adsorption on activated carbon from a new precursor hazelnut husks. Desalination 228: 108-113.

  • Kidalova L Stevulova N Terpakova E (2015) Influence of water absorption on the selected properties of hemp hurds composites. Pollack Periodica 10: 123-132.

  • Leng L Yuan X Zeng G Shao J Chen X Wu Z Peng X (2015) Surface characterization of rice husk bio-char produced by liquefaction and application for cationic dye (Malachite green) adsorption. Fuel 155: 77-85.

  • Ngah WW Hanafiah MAKM (2008) Removal of heavy metal ions from wastewater by chemically modified plant wastes as adsorbents: A review. Bioresour. Technol. 99: 3935-3948.

  • Rahman MS Islam MR (2009) Effects of pH on isotherms modeling for Cu (II) ions adsorption using maple wood sawdust. Chem. Eng. J. 149: 273-280.

  • Ricordel S Taha S Cisse I Dorange G (2001) Heavy metals removal by adsorption onto peanut husks carbon: characterization kinetic study and modeling. Separ. Purif. Technol. 24: 389-401.

  • Schwanninger M Rodrigues JC Pereira H Hinterstoisser B (2004) Effects of short-time vibratory ball milling on the shape of FT-IR spectra of wood and cellulose. Vib. Spectros. 36: 23-40.

  • Šćiban M Radetić B Kevrešan Ž Klašnja M (2007) Adsorption of heavy metals from electroplating wastewater by wood sawdust. Bioresour. Technol. 98: 402-409.

  • Shukla A Zhang YH Dubey P Margrave JL Shukla SS (2002) The role of sawdust in the removal of unwanted materials from water. J. Hazard. Mater. 95: 137-152.

  • Singovszka E Balintova M Holub M (2016) Heavy metal contamination and its indexing approach for sediment in Smolnik creek (Slovakia). Clean Technol. Environ. Policy 18: 305-313.

  • Stevulova N Cigasova J Estokova A Terpakova E Geffert A Kacik F Singovszka E Holub M (2014) Properties characterization of chemically modified hemp hurds. Materials 7: 8131-8150.

  • Sud D Mahajan G Kaur MP (2008) Agricultural waste material as potential adsorbent for sequestering heavy metal ions from aqueous solutions – A review. Bioresour. Technol. 99: 6017-6027.

  • Vieira RH Volesky B (2000) Biosorption: a solution to pollution? Internat. Microbiol. 3: 17-24.

  • Zhang LI Zhao LI Yu Y Chen C (1998) Removal of lead from aqueous solution by non-living Rhizopus nigricans. Water Res. 32: 1437-1444.

  • Zhang P Dong SJ Ma HH Zhang BX Wang YF Hu XM (2015) Fractionation of corn stover into cellulose hemicellulose and lignin using a series of ionic liquids. Ind. Crops Prod.76: 688-696.

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CiteScore 2018: 0.68

SCImago Journal Rank (SJR) 2018: 0.173
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