The effect of different fabrication techniques on the formation of electroactive β-phase polyvinylidene fluoride (PVDF) has been investigated. Films with varying concentration of PVDF and solvent - dimethyl formamide (DMF) were synthesized by tape casting and solvent casting techniques. The piezoelectric β-phase as well as non polar β-phase were observed for both the tape cast and solvent cast films from X-ray diffraction (XRD) micrographs and Fourier transform infra-red spectroscopy (FT-IR) spectra. A maximum percentage (80 %) of β-phase was obtained from FT-IR analysis for a solvent cast PVDF film. The surface morphology of the PVDF films was analyzed by FESEM imaging. The dielectric properties as a function of temperature and frequency and the ferroelectric hysteresis loop as a function of voltage were measured. An enhancement in the value of the dielectric constant and polarization was obtained in solvent cast films.