Magnetic resonance study of γ-Fe2O3 nanoparticles dressed in oxygen based free radicals

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Abstract

Two composites consisting of γ-Fe2O3 (maghemite) nanoparticles covered by two different oxygen-based free radicals derived from a 4-(methylamino)phenol sulphate and 8-hydroxy-1,3,6-trisulfonic trisodium salt acid were prepared and investigated by the magnetic resonance method in the 4–300 K range. Both composites displayed broad and very intense ferromagnetic resonance (FMR) lines originating from γ-Fe2O3 agglomerated nanoparticles. The FMR spectrum was fitted satisfactorily at each temperature by two Landau-Lifshitz functions reflecting the existence of magnetic anisotropy in the investigated system. The temperature dependence of the obtained FMR parameters (resonance field, linewidth, integrated intensity) was studied and the results were interpreted in terms of magnetic interactions between free radicals and nanoparticle agglomerates. A comparison with previously studied similar systems containing maghemite nanoparticles was made and conclusions about the role of free radicals were drawn.

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  • [1] Pankurst Q.A. Connoly J. Jones S.K. Dobson J. J. Phys. D Appl. Phys. 36 (2003) R167. http://dx.doi.org/10.1088/0022-3727/36/13/201

  • [2] Alexiou C. Jurgons R. Seliger G. Iro H. J. Nanosci. Nanotechnol. 6 (2006) 2762. http://dx.doi.org/10.1166/jnn.2006.464

  • [3] Majoral J. P. Caminade A. M. Chem Rev. 99 (1999) 845. http://dx.doi.org/10.1021/cr970414j

  • [4] Bourlinos A. B. Dallas P. Sanakis Y. Stamopoulos D. Trapalis C. Niarchos D. Eur. Polym. J. 42 (2006) 2940. http://dx.doi.org/10.1016/j.eurpolymj.2006.07.025

  • [5] Shahid M. Ashraf R. S. Klemm E. Sensfuss S. Macromolecules 39 (2006) 7844. http://dx.doi.org/10.1021/ma061231e

  • [6] Shin R. Y. C. Kietzke T. Sudhakar S. Dodabalapur A. Chen Z. K. Sellinger A. Chem. Mater. 19 (2007) 1892. http://dx.doi.org/10.1021/cm070144d

  • [7] Bourlinos A.B. et al. Carbon 44 (2006) 1906. http://dx.doi.org/10.1016/j.carbon.2006.02.008

  • [8] Guskos N. Zolnierkiewicz G. Typek J. Guskos A. Petridis D. J. Non-Cryst. Solids 354 (2008) 4211. http://dx.doi.org/10.1016/j.jnoncrysol.2008.06.035

  • [9] Guskos N. Zolnierkiewicz G. Typek J. Guskos A. Petridis D. Adv. Rev. Mat. Sci. 23 (2010) 164.

  • [10] Dallas P. Tucek J. Jancik D. Kolar M. Panacek A. Zboril R. Adv. Funct. Mater. 20 (2010) 2347. http://dx.doi.org/10.1002/adfm.200902370

  • [11] Guskos N. Zolnierkiewicz G. Typek J. Guskos A. Berczynski P. Petridis D. Centr. Eur. J. Phys. 90 (2012) 166–171. http://dx.doi.org/10.2478/s11534-011-0085-5

  • [12] Guskos N. et al. J. Appl. Phys. 93 (2003) 9834. http://dx.doi.org/10.1063/1.1574593

  • [13] Kliava J. Electron Magnetic Resonance of Nanoparticles: Superparamagnetic Resonance in Magnetic Nanoparticles (ed S. P. Gubin) Wiley-VCH Verlag GmbH & Co. KGaA Weinheim Germany (2009).

  • [14] Guskos N. et al. Rev. Adv. Mat. Sci. 14 (2007) 157.

  • [15] Guskos N. Zolnierkiewicz G. Typek J. Guskos A. Czech Z. Rev. Adv. Mat. Sci. 14 (2007) 57.

  • [16] Guskos N. Typek J. Maryniak M. Roslaniec Z. Petridis D. and Kwiatkowska M. Mater. Sci.-Poland 23 (2005) 972.

  • [17] Bodziony T. Guskos N. Typek J. Roslaniec Z. Narkiewicz U. and Maryniak M. Mater. Sci.-Poland 23 (2005) 1055.

  • [18] Guskos N. et al. J. Appl. Phys. 99 (2006) 084307. http://dx.doi.org/10.1063/1.2189216

  • [19] Narkiewicz U. et al. Mater. Sci.-Poland 24 (2006) 1067.

  • [20] Guskos N. et al. J. Nanosci. Nanotech. 8 (2008) 2127. http://dx.doi.org/10.1166/jnn.2008.063

  • [21] Guskos N. et al. J. Non-Cryst. Solids. 354 (2008) 4401. http://dx.doi.org/10.1016/j.jnoncrysol.2008.06.059

  • [22] Typek J. Guskos N. Szymczyk A. Petridis D. J. Non-Cryst. Solids. 354 (2008) 4256. http://dx.doi.org/10.1016/j.jnoncrysol.2008.06.090

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