<abstract xmlns="http://www.w3.org/1999/xhtml">Granitic plutons (the Dolina Będkowska valley and Pilica area) were found in a few boreholes in the Małopolska Block (MB). These granitic rocks may represent apical parts (apophyses) of a great magmatic bodies (batholiths) located in deeper level of the Ediacaran/Paleozoic basement. They are described as ‘stitching intrusions’, generated during/after collision in Carboniferous/Permian period (~300 Ma) between the Upper Silesian Block (USB) and the Małopolska Block (MB).These rocks are fresh, unaltered granodiorites that are pale grey in colour. They have holocrystalline, medium- to coarse-grained structure and massive texture. For the first time, several mafic microgranular enclaves (MME), varying in size and colour, were found in the granodioritic host (HG). The occurrence of MME in the host granodioritic rocks is evidence of a mingling process between mafic and felsic magmas.The MME are pale/dark grey in colour, fine-grained rocks with ‘porphyritic’ textures. They consist of large megacrysts/xenocrysts of plagioclase, quartz, alkali feldspars and the fine-grained groundmass of pseudo-doleritic textures (lath-shaped plagioclases, blade-shaped amphiboles/biotites). According to their modal/mineral composition, they represent Q-diorites and tonalites.The MME, similar to the host granodiorites (HG), are I-type rocks, exhibit high Na2O content >3.2 wt%; normative diopside or normative corundum occurs (mainly &lt;1%). They are metaluminous to slightly peraluminous (ASI &lt;1.1) and have calc-alkaline, medium-K to high-K character. They generally belong to magnesian series (#Mg=0.20-0.40) and have low agpaitic index (&lt;0.87). They are low evolved magmatic rocks. The rocks studied are enriched in LREEs (La, Ce, Sm) compared to HREEs. The Eu* negative anomaly and high Sr contents point to varying degrees of plagioclase fractionation connected to the mixing process rather than simple fractional crystallization. Both rocks studied (HG and MME) are characterized by a high content of LILEs (K, Ba, Rb) in normalized patterns and a low HFS/LIL elements ratio (Ta, Nb)/(K, Rb, La). The projection points of the rocks studied plot in different fields of various petrochemical diagrams: mainly in the arc granites that are rare in the pre-collisional granites as well as the syn-subductional to post-collisional granites fields.For the first time, inner textures in rock-forming minerals related to mixing processes are described both in the granodioritic host (HG) and in the MME. Mantled boxy cellular plagioclase megacrysts with ‘old cores’ of labradorite composition, and amphibole aggregates with titanite and opaque minerals, represent peritectic rather than primary residual minerals. The plagioclase, quartz and alkali feldspar megacrysts/xenocrysts were mechanically transferred from the granodioritic host (HG) to MME. The presence of lath-shaped plagioclases, blade-shaped amphiboles/biotites and acicular-shaped apatites in the groundmass of the MME is evidence of undercooling of hot mafic blobs in a relatively cold granodioritic magma chamber. The MME were hybridized by leucocratic melt squeezed from the granodioritic magma in a later stage of the mixing process (quartz and alkali crystals in the interstices in the MME groundmass). In the granodiorites (HG), the spike and spongy cellular zones as well as biotite/amphibole zones in plagioclase megacrysts are connected to the mixing process.Both of the rocks studied are characterized by different amounts of major elements (SiO2, Na2O and K2O), trace elements (Ni, Cr, V, Ti and P), #Mg and modified alkali-lime index (MALI) that is related to their origins from different sources. On the other hand, they have similar chondrite-normalized patterns (for trace elements and REE), LILEs contents (Sr, Ba, Rb), aluminum saturation index (ASI) and isotopic signatures (high 86Sr/87Sr (0.079-0.713) and low 143Nd/144Nd (0.512) values but lower than in continental crust), which are evidence of the strong hybridisation of mafic enclaves by the granodioritic host magma. The parental rocks of both rocks studied have a similar mafic signature but were generated in different sources: the host granodiorites (HG) magma in lower continental crust rocks, and the MME magma in enriched upper mantle. The MME crystallized from strongly hybridized magma of intermediate compositions (Q-diorite, tonalite) rather than from primary mafic magma. The host granodiorites (HG) originated from completely homogenized crustal granodioritic magma which inherited its geochemical signature from ancient arc-rocks in a subduction-related setting </abstract>

Petrology and geochemistry of granitoids and their mafic micogranular enclaves (MME) in marginal part of the Małopolska Block (S Poland)

<abstract xmlns="http://www.w3.org/1999/xhtml">The bromide analogue of pyromorphite Pb5(PO4)3Br was synthesized and characterized by X-ray diffraction, infrared spectroscopy and scanning electron microscopy. The solubility of the brompyromorphite was measured at 25°C and pH values of 2.0, 2.6 and 3.2. For the 3 pH measurements, the average solubility product, log KSP, for the reaction Pb5(PO4)3Br ⇔ 5Pb2+ + 3PO- 3- + Br- at 25ºC is -77.38 ± 0.70. The free energy of formation, ΔG°f,298, calculated from this measured solubility product is -3724.7 ± 4.3 kJ mol−1. These results confirm that brompyromorphite is more soluble than pyromorphite. </abstract>

Synthesis and solubility of brompyromorphite Pb5(PO4)3Br

<abstract xmlns="http://www.w3.org/1999/xhtml">A simple photometric method for copper (II) analysis using monosodium glutamate (MSG) is presented. The method is technically simple, inexpensive, quantitative, and makes use of readily available reagents. The rapid reaction of copper (II) with glutamate in aqueous solution at pH 10 to form a blue complex serves as a basis for the determination of copper (II) in the range of 10-500 μg/ml. Copper recovery is > 82%. The method could be used to determine copper (II) concentrations in iron ore samples. </abstract>

Simple method of copper analysis using monosodium glutamate and its application in ore analysis

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Mineralogia

 Mineralogia (ISSN: 1899-8291, e-ISSN: 1899-8526), a free open access journal, publishes original research and review papers from broad fields of geochemistry, mineralogy, petrology, technical, experimental and applied mineralogy, and environmental sciences. Mineralogia (formerly Mineralogia Polonica) is an English language journal with 50 years long tradition. The journal’s subtitle, Geochemical, Mineralogical and Petrological Research, indicates the open character of the journal. The regular series Mineralogia is accompanied by the irregular series, including Mineralogia - Special Papers (containing conference abstracts) and Thematic Collections.    Publications in the scope of widely understood mineralogical sciences (mineralogy, petrology, geochemistry, environmental sciences, applied mineralogy, etc.)   Original research and review papers, letters (a short research paper), short notes (a brief communication), book reviews, and letters to editors with comments on papers published in Mineralogia    First issue of Mineralogia Polonica, the official Journal of the Mineralogical Society of Poland, was published in 1970 soon after foundation of the Society in 1969. Mineralogia Polonica, publishing in English from its beginning, has been very important for development of mineralogical sciences in Poland, exchange of scientific journals and international collaboration. Based on a long discussion with our colleagues from abroad we have noticed that the title suggests that the journal is focused on local mineralogical problems from Poland. To avoid this misunderstanding we have decided to modify the title and accordingly the journal cover. The new and simple title Mineralogia (with subtitle Geochemical, Mineralogical and Petrological Research) indicates an open character of the journal. We intend to publish original papers, review papers and short notes from broad fields of geochemistry, mineralogy, petrology, technical, experimental and applied mineralogy, environmental geochemistry and mineralogy. We have also decided to introduce changes in the organization of our Editorial Board to ensure high scientific level of journal and relatively short time-span between paper submission and publication.   The journal facilitates communication and promotes scientific research in the scope of:    descriptive mineralogy   experimental mineralogy   igneous petrology   metamorphic petrology   sedimentary petrology   hard rock geochemistry   geochronology and petrochronology   environmental mineralogy and geochemistry    Why subscribe and read    excellent source of outstanding interdisciplinary research papers in mineralogy, petrology, geochemistry and related disciplines;   over fifty years of publishing;   offers high-quality electronic publications (eISSN 1899-8526);   special issues publishing reviewed abstracts from conferences co-organized by the Mineralogical Society of Poland;    Why submit    fast, fair, and constructive single-blind peer review and editing;   no processing and no publication charges;   language-correction services for authors from non-English speaking regions;      Archiving   Sciendo archives the contents of this journal in Portico - digital long-term preservation service of scholarly books, journals and collections.   Plagiarism Policy   The editorial board is participating in a growing community of Similarity Check System's users in order to ensure that the content published is original and trustworthy. Similarity Check is a medium that allows for comprehensive manuscripts screening, aimed to eliminate plagiarism and provide a high standard and quality peer-review process.   Funding   Authors should list all funding sources in the Acknowledgments section.   ORCID   Mineralogia journal requires ORCID.   Ethical considerations   This journal follows the basic principles of the publishing process as documented by the Committee on Publication Ethics (COPE). The COPE’s guidelines focus mainly on issues related to publication in the medical literature; thus, not all the points are relevant to the Mineralogia journal. Although the essential ethical concerns considered while publishing in Mineralogia align with the COPE guidelines, Mineralogia is not bound by their defined processes.   Mineralogia otrzymała dofinansowanie z MNiE na lata 2022-2024 w ramach programu Rozwój czasopism naukowych (RCN/SN/0190/2021/1).   Ministry of Science and Higher Education co-financed Mineralogia in 2022-2024 as part of the Development of Scientific Journals call (Rozwój czasopism naukowych; RCN/SN/0190/2021/1). 

Mineralogia

Volume 43 (2012): Issue 1-2 (March 2012)

Petrology and geochemistry of granitoids and their mafic micogranular enclaves (MME) in marginal part of the Małopolska Block (S Poland)

Synthesis and solubility of brompyromorphite Pb₅(PO₄)₃Br

Simple method of copper analysis using monosodium glutamate and its application in ore analysis

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