Corrosion behavior of wrought magnesium alloys AZ31 and AZ61 in Hank’s solution

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Abstract

Corrosion behavior of wrought magnesium alloys AZ31 and AZ61 was studied in Hank’s solution. Potentiodynamic curves measured after short-term of exposure showed higher corrosion resistance of AZ31 magnesium alloy in comparison with AZ61 magnesium alloy. On the contrary, long-term tests measured by electrochemical impedance spectroscopy showed higher corrosion resistance of AZ61 magnesium alloy in comparison with AZ31 magnesium alloy.

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  • 1. Jung O.; Smeets R.; Porchetta D.; Kopp A.; Ptock Ch.; Müller U.; Heiland M.; Schwade M.; Behr B.; et al. Optimized in vitro procedure for assessing the cytocompatibility of magnesium-based biomaterials. Acta Biomaterialia 2015 23 (1) 354-363.

  • 2. Farraro K. F.; Kim K. E.; Woo S. L.; Flowers J. R.; McCullough M. B. Revolutionizing orthopaedic biomaterials: The potential of biodegradable and bioresorbable magnesium-based materials for functional tissue engineering. Journal of Biomechanics 2014 47 (9) 1979-1986.

  • 3. Mhaede M.; Pastorek F.; Hadzima B. Infl uence of shot peening on corrosion properties of biocompatible magnesium alloy AZ31 coated by dicalcium phosphate dihydrate (DCPD). Materials Science and Engineering: C 2014 39 330-335.

  • 4. Witte F.; Kaese V.; Haferkamp H.; Switzer E.; Lindenberg A. M.; Wirth C. J.; Windhagen H. In vivo corrosion of four magnesium alloys and the associated bone response. Biomaterials 2005 26 3557-3563.

  • 5. Li W.; Guan S.; Chen J.; Hu J.; Chen S.; Wang L.; Zhu S. Preparation and in vitro degradation of the composite coating with high adhesion strength on biodegradable Mg- Zn-Ca alloy Materials Characterization 2011 62 (12) 1158-1165.

  • 6. Homayun B.; Afshar A. Microstructure mechanical properties corrosion behavior and cytotoxicity of Mg-Zn- Al-Ca alloys as biodegradable materials. Journal of Alloys and Compounds 2014 607 1-10.

  • 7. Bakhsheshi-Rad H. R.; Idris M. H.; Abdul-Kadir M. R.; Ourdjini A.; Medraj M.; Daroonparvar M.; Hamzah E. Mechanical and bio-corrosion properties of quaternary Mg-Ca-Mn-Zn alloys compared with binary Mg-Ca alloys. Materials & Design 2014 53 283-292.

  • 8. Song G. Control of biodegradation of biocompatable magnesium alloys. Corrosion Science 2007 49 (4) 1696-1701.

  • 9. Plum L. M.; Rink L.; Haase H. The Essential Toxin: Impact of Zinc on Human Health. International Journal of Environmental Research and Public Health 2010 7 (4) 1342-1365.

  • 10. Salleh E. M.; Zuhailawati H.; Ramakrishnan S.; Gepreel M. A. H. A statistical prediction of density and hardness of biodegradable mechanically alloyed Mg-Zn alloy using fractional factorial design. Journal of Alloys and Compounds 2015 644 476-484.

  • 11. Li Q.; Jiang G.; Wang C.; Dong J.; He G. Mechanical degradation of porous titanium with entangled structure filled with biodegradable magnesium in Hanks‘ solution. Materials Science and Engineering: C 2015 57 349-354.

  • 12. Brar H. S.; Wong J.; Manuel M. V. Investigation of the mechanical and degradation properties of Mg-Sr and Mg-Zn-Sr alloys for use as potential biodegradable implant materials. Journal of the Mechanical Behavior of Biomedical Materials 2012 7 87-95.

  • 13. Berglund I. S.; Brar H. S.; Dolgova N.; Acharya A. P.; Keselowsky B. G.; Sarntinoranont M.; Manuel M. V. Synthesis and characterization of Mg-Ca-Sr alloys for biodegradable orthopedic implant applications. Journal of Biomedical Materials Research Part B: Applied Biomaterials 2012 100B (6) 1524-1534.

  • 14. Zhang F.; Ma A.; Song D.; Jiang J.; Lu F.; Zhang L.; Yang D.; Chen J.; Improving in-vitro biocorrosion resistance of Mg-Zn-Mn-Ca alloy in Hank‘s solution through addition of cerium. Journal of Rare Earths 2015 33 (1) 93-101.

  • 15. Johnston S.; Shi Z.; Atrens A. The infl uence of pH on the corrosion rate of high-purity Mg AZ91 and ZE41 in bicarbonate buffered Hanks‘ solution. Corrosion Science 2015 101 182-192.

  • 16. Abidin N. I. Z.; Rolfe B.; Owen H.; Malisano J.; Martin D.; Hofstetter J.; Uggowitzer P. J.; Atrens A. The in vivo and in vitro corrosion of high-purity magnesium and magnesium alloys WZ21 and AZ91. Corrosion Science 2013 75 354-366.

  • 17. Han G.; Lee J. Y.; Kim Y. Ch.; Park J. H.; Kim D. I.; Han H. S.; Yang S. J.; Seok H. K. Preferred crystallographic pitting corrosion of pure magnesium in Hanks’ solution. Corrosion Science 2012 63 316-322.

  • 18. Zeng R. Ch.; Sun L.; Zheng Y. F.; Ciu H. Z.; Han E. H. Corrosion and characterisation of dual phase Mg-Li-Ca alloy in Hank’s solution: The influence of microstructural features. Corrosion Science 2014 79 69-82.

  • 19. Ng W. F.; Chiu K. Y.; Cheng F. T. Effect of pH on the in vitro corrosion rate of magnesium degradable implant material. Materials Science and Engineering: C 2010 30 (6) 898-903.

  • 20. Bukovinová L.; Hadzima B. Electrochemical characteristics of magnesium alloy AZ31 in Hank’s solution. Corrosion Engineering Science and Technology 2012 47 (5) 352-357.

  • 21. Vander Voort George F. Metallography principles and practice; Materials Park OH: ASM International c1999.

  • 22. Liu F.; Song Y. W.; Shan D. Y.; Han E. H. Corrosion behavior of AZ31 magnesium alloy in simulated acid rain solution. Transactions of Nonferrous Metals Society of China 2010 20 (2) s638-s642.

  • 23. Jinfeng D.; Guangsheng H.; Yanchun Z.; Bei W. Electrochemical Performance of AZ31 Magnesium Alloy under Different Processing Conditions. Rare Metal Materials and Engineering 2014 43 (2) 316-321.

  • 24. Mathieu S.; Rapin C.; Steinmetz J.; Steinmetz P.: A corrosion study of the main constituent phases of AZ91 magnesium alloys. Corrosion Science 2003 45 (12) 2741-2755.

  • 25. Pardo A.; Merino M. C.; Coy A. E.; Arrabal R.; Viejo F.; Matykina E. Corrosion behaviour of magnesium/aluminium alloys in 3.5 wt.% NaCl. Corrosion Science 2008 50 (3) 823-834.

  • 26. Song Y.; Shan D.; Chen R.; Zhang F.; Han E. H. Biodegradable behaviors of AZ31 magnesium alloy in simulated body fluid. Materials Science and Engineering: C 2009 29 (3) 1039-1045.

  • 27. Song G.; Atrens A.; Dargusch M. Infl uence of microstructure on the corrosion of diecast AZ91D. Corrosion Science 1998 41 (2) 249-273.

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