Published Online: Jul 27, 2016
Page range: 598 - 602
DOI: https://doi.org/10.1515/kbo-2016-0103
Keywords
© 2015 Daniela Babuşca et al., published by De Gruyter Open
This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.
The wavenumbers in the maximum of intramolecular charge transfer (ICT) visibile band of two pyridazinium ylids binary solutions were analized using Kamlet and Taft empirical parameters and the Hildebrand’s solubility parameter. The Hildebrand’s solubility parameter values, δH2, measures the energy needed to separate the solvent molecules. A linear solvation energy relationship (LSER) allows separating the contributions of different types of interactions to the total spectral shift. The supply of universal and specific interactions as well as the supply of solvent-solvent interactions to the total spectral shifts was calculated.