The Effect of Electric Field on Nanofibers Preparation in Cylindrical-Electrode-Assisted Solution Blowing Spinning

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Cylindrical-electrode-assisted solution blowing spinning (CSBS) is a novel nanofiber preparation method. The electric field of CSBS not only is one of the main innovations of this technology but also plays a key role in the preparation of nanofibers. In this article, the electric field of CSBS and the influences of electric field on the preparation of nanofibers were studied systematically for the first time by simulations, theoretical analyses, and experiments. This paper innovatively established the coaxial capacitor model for studying the CSBS electric field. The effects of electric field on the preparation and morphology of CSBS nanofibers were theoretically investigated by using this model. The theoretical formulas that can express the relationships between the various electric field variables were obtained. The electric field strength distribution, voltage distribution, and the relationships between the electric field parameters of CSBS were obtained by finite element simulations. The simulations’ results show that reducing the diameter of cylinder (DC) or increasing the voltage increase the electric field strength of the jet surface. Experimental results reveal that increasing voltage or reducing DC can reduce the diameter of nanofibers. The experimental and simulation results prove the correctness of the theoretical research conclusions. The theoretical and simulation conclusions of this paper lay a theoretical foundation for further study of CSBS electric field. The experimental conclusions can directly guide the controllable preparation of CSBS nanofibers.

[1] Medeiros, E. S., Glenn, G. M., Klamczynski, A. P., Orts, W. J., Mattoso, L. H. C. (2009). Solution blow spinning: A new method to produce micro- and nanofibers from polymer solutions. Journal of Applied Polymer Science, 113(4), 2322-2330.

[2] Tutak, W., Sarkar, S., Lin-Gibson, S, Farooque, T. M., Jyotsnendu, G., et al. (2013). The support of bone marrow stromal cell differentiation by airbrushed nanofiber scaffolds. Biomaterials. 34(10), 2389-2398.

[3] Polat, Y., Pampal, E. S., Stojanovska, E., Simsek, R., Hassanin, A., et al., (2016). Solution blowing of thermoplastic polyurethane nanofibers: A facile method to produce flexible porous materials. Journal of Applied Polymer Science, 133(9), n/a-n/a.

[4] Zhang, X., Shi, M. (2018). Flame retardant vinylon/poly(m phenylene isophthalamide) blended fibers with synergistic flame retardancy for advanced fireproof textiles. Journal of Hazardous Materials, 365, 9-15.

[5] Hsiao, H.-Y., Huang, C.-M., Hsu M.-Y., Chen, H. (2011). Preparation of high-surface-area PAN-based activated carbon by solution-blowing process for CO2 adsorption. Separation and Purification Technology, 82, 19-27.

[6] Tao, X., Zhou, G., Zhuang, X, Cheng, B., Li, X., et al. (2015). Solution blowing of activated carbon nanofibers for phenol adsorption. RSC Advances,. 5(8), 5801-5808.

[7] Shi, S., Zhuang, X., Chengab, B., Wang, X. (2013). Solution blowing of ZnO nanoflake-encapsulated carbon nanofibers as electrodes for supercapacitors. Journal of Materials Chemistry A, 1(44), 13779.

[8] Zhuang, X., Jia, K., Cheng, B., Feng, X., Shi, S., et al. (2014). Solution blowing of continuous carbon nanofiber yarn and its electrochemical performance for supercapacitors. Chemical Engineering Journal, 237, 308-311.

[9] Xu, X., Li, L., Wang, H., Li, X., Zhuang, X. (2015). Solution blown sulfonated poly(ether ether ketone) nanofiber– Nafion composite membranes for proton exchange membrane fuel cells. RSC Advances, 5(7), 4934-4940.

[10] Wang, H., Zhuang, X., Li, X., Wang, W., Wang, Y., et al. (2015). Solution blown sulfonated poly(ether sulfone)/poly(ether sulfone) nanofiber-Nafion composite membranes for proton exchange membrane fuel cells. Journal of Applied Polymer Science, 132(38), n/a-n/a.

[11] Behrens, A. M., Casey, B. J., Sikorski, M. J., Wu, K. L., Tutak, W., et al. (2014). In situ deposition of PLGA nanofibers via solution blow spinning. ACS Macro Letters, 3(3), 249-254.

[12] Abdal-hay, A., Sheikh, F. A., Lim, J. K. (2013). Air jet spinning of hydroxyapatite/poly(lactic acid) hybrid nanocomposite membrane mats for bone tissue engineering. Colloids and Surfaces B: Biointerfaces, 102, 635-643.

[13] Bilbao-Sainz, C., Chiou, B.-S., Valenzuela-Medina, D., Du, W. X., Gregorski, K. S., et al. (2014). Solution blow spun poly(lactic acid)/hydroxypropyl methylcellulose nanofibers with antimicrobial properties. European Polymer Journal, 54, 1-10.

[14] Li, L., Kang, W., Zhuang, X., Shi, J., Zhao, Y., et al. (2015). A comparative study of alumina fibers prepared by electro-blown spinning (EBS) and solution blowing spinning (SBS). Materials Letters, 160, 533-536.

[15] Bolbasov, E. N., Stankevich, K. S., Sudarev, E. A., Bouznik, V. M., Kudryavtseva, V. L., et al. (2016). The investigation of the production method influence on the structure and properties of the ferroelectric nonwoven materials based on vinylidene fluoride – tetrafluoroethylene copolymer. Materials Chemistry and Physics, 182, 338-346.

[16] Zheng, W., Zheng, W., Shi, C., Wang, H. (2019). Cylindrical-electrode-assisted solution blowing for nanofiber spinning. Journal of Applied Polymer Science, 136(8), 47087.

[17] Doshi, J., Reneker, D. H. (1995). Electrospinning process and applications of electrospun fibers. Journal of Electrostatics, 35(2), 151-160.

Autex Research Journal

The Journal of Association of Universities for Textiles (AUTEX)

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IMPACT FACTOR 2018: 0.927
5-year IMPACT FACTOR: 1,016

CiteScore 2018: 1.21

SCImago Journal Rank (SJR) 2018: 0.395
Source Normalized Impact per Paper (SNIP) 2018: 1.044


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