Air quality monitoring is the most important environmental factor to be considered because it is the fastest way that helps pollutant transport into the environment. The development of human society has led to a negative anthropogenic and technogenic impact on air quality, resulting into a significant series of adverse effects on human health, flora, fauna and ecosystems in general. In this paper it is presentd the research work performed to monitor carbon monoxide emissions from motor vehicles in traffic, in a densely populated area in Sibiu. Also, in the paper it is described, the research findings conducted in accordance with national and European legislation. In our research we used GIS software, Geomedia Professional.