Effects of Modifying Agents on the Dyeability of Cotton Fabric using Malachite Green Dye

Abstract

Changes in thermodynamic parameters as a result of modifying agents on dye uptake of cotton fabric using malachite green (MG) dye was investigated in this study. Five modifying agents {Acetic acid (CH3COOH), hydrated Sodium carbonate (Na2CO3.10H2O), Sodium Chloride (NaCl), Ammonium sulphate ((NH4)2SO4) and Hydrogen peroxide (H2O2)} were used on cotton fabric. The equilibrium exhaustions (%E) were determined before and after modification of the cotton fabric at different concentrations which were 88.24%, 80%, 77.14%, 65.10% and 30.88% for CH3COOH, NaCl, (NH4)2SO4, Na2CO3.10H2O and H2O2 respectively. The results also showed a correlation between the standard affinity(-Δμθ) of dye on cotton fabric and the equilibrium exhaustion. The values of entropy (ΔSθ) and enthalpy (ΔHθ) change revealed the feasibility (spontaneity) and exothermic nature of the reaction. The optimum parameters were attained in acidic solution (CH3COOH) at the highest temperature (70 °C) of dyeing as it showed the highest % efficiency of 88.24%. This work established that modification of cotton fabric with modifying agents is one of the best route to improve the affinity between dye and fabric as it reduces stress, amount of dyes wasted in dyeing, time required to achieve satisfactory results leading to a cost effective environmental friendly approach in the field of cotton dyeing.

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  • Adebayo, G., Adekola, F., Olatunji, G., Bello, I., 2010, Some thermodynamic parameters of two indigenous mineral dyes applied on wool material. Bulletin of Pure & Applied Sciences 29, 77.

  • Baltazar-Y-Jimenez, A., Bismarck, A., 2007, Surface modification of lignocellulosic fibres in atmospheric air pressure plasma. Green Chemistry 9, 1057-1066.

  • Bashar, M.M., Khan, M.A., 2013, An overview on surface modification of cotton fiber for apparel use. Journal of Polymers and the Environment 21, 181-190.

  • Bello, I., Bello, K., Peters, O., Bello, O., 2009, Synthesis, Spectroscopic, Thermodynamic And Dyeing Properties Of Disperse Dyes Derived From 2-Amino-4-Trifluoromethylbenzothiazole. Report and Opinion 1, 58-66.

  • Bello I. A. Peters O. A., Nkeonye P. O. and Sunmonu O. K., 2002, Kinetics and Thermodynamics Studies of an Acid Dye on Modified Nylon 6 Fabrics. J. Pure Appl. Sci., 5: 309-314.

  • Bello, I.A., Giwa, A.-r.A., Aderinto, S.O., Olabintan, A., 2013, Effect Of Position of Substituents on the Exhaustion and Thermodynamic Parameters of 6 Monoazo Acid and Disperse Dyes on Nylon 6.

  • Bello I. A., Peters O. A., Giwa A. A., Abdul-Hammed M., Adeoye D. O., 2014, Effect of modifying agents on percentage equilibrium exhaustion of an acid dye on nylon fabric Australian J. Basic Appl. Sci. 8 (1), 552-559

  • El-Molla, M., Badawy, N., AbdEl-Aal, A., El-Bayaa, A., El-Shaimaa, H., 2011, Dyeability of cationised cotton and nylon 6 fabrics using acid dyes.

  • Fang, L., Zhang, X., Ma, J., Sun, D., Zhang, B., Luan, J., 2015, Ecofriendly cationic modification of cotton fabrics for improving utilization of reactive dyes. RSC Advances 5, 45654-45661.

  • Fang, L., Zhang, X., Sun, D., 2013, Chemical modification of cotton fabrics for improving utilization of reactive dyes. Carbohydrate polymers 91, 363-369.

  • Gharbani, P., Tabatabaii, S., Mehrizad, A., 2008, Removal of Congo red from textile wastewater by ozonation. International Journal of Environmental Science & Technology 5, 495-500.

  • Goyal, P., Sharma, P., Srivastava, S., Srivastava, M., 2008, Saraca indica leaf powder for decontamination of Pb: removal, recovery, adsorbent characterization and equilibrium modeling. International Journal of Environmental Science & Technology 5, 27-34.

  • Hasani, M., Westman, G., Potthast, A., Rosenau, T., 2009, Cationization of cellulose by using N-oxiranylmethyl-N-methylmorpholinium chloride and 2-oxiranylpyridine as etherification agents. Journal of applied polymer science 114, 1449-1456.

  • Hyde, K., Dong, H., Hinestroza, J.P., 2007, Effect of surface cationization on the conformal deposition of polyelectrolytes over cotton fibers. Cellulose 14, 615-623.

  • Igwe, J.C., Abia, A., Ibeh, C., 2008, Adsorption kinetics and intraparticulate diffusivities of Hg, As and Pb ions on unmodified and thiolated coconut fiber. International Journal of Environmental Science & Technology 5, 83-92.

  • Kamel, M., El Zawahry, M., Ahmed, N., Abdelghaffar, F., 2009, Ultrasonic dyeing of cationized cotton fabric with natural dye. Part 1: Cationization of cotton using Solfix E. Ultrasonics Sonochemistry 16, 243-249.

  • Kawee S. and Papapida P., 1998, Method of Chemical Modification of Cellulosic Fibers to improve their dyeability with reactive dyes J. Sci. Res. Chula. Univ., 23 (2): 143-153

  • Khattri, S., Singh, M., 1999, Colour removal from dye wastewater using sugar cane dust as an adsorbent. Adsorption science & technology 17, 269-282.

  • Liu, Z.-T., Yang, Y., Zhang, L., Liu, Z.-W., Xiong, H., 2007, Study on the cationic modification and dyeing of ramie fiber. Cellulose 14, 337-345.

  • Ma, W., Zhang, S., Tang, B., Yang, J., 2005, Pretreatment of cotton with poly (vinylamine chloride) for salt-free dyeing with reactive dyes. Coloration Technology 121, 193-197.

  • Mahbubul B. M. and Khan, M.A., 2013, An Overview on Surface Modification of Cotton Fiber for Apparel Use J Polym Environ 21, 181-190.

  • Mansour R., Farouk M. and Bechir1 E. M., 2014, Dyeing Properties of Cationized and non Cationized Cotton Fabrics Dyed with Vitis vinifera L. Leaves Extract, Middle-East. J. Sci. Res., 21 (9),1600-1604.

  • Micheal, M., Tera, F., Ibrahim, S., 2002, Effect of chemical modification of cotton fabrics on dyeing properties. Journal of applied polymer science 85, 1897-1903.

  • Rattanaphani, S., Chairat, M., Bremner, J.B., Rattanaphani, V., 2007, An adsorption and thermodynamic study of lac dyeing on cotton pretreated with chitosan. Dyes and pigments 72, 88-96.

  • Rym, M., Farouk, M., Bechir, E.M., 2016, Dyeing properties of cationized and non-cationized cotton fabrics dyed with Vitis vinifera L. leaves extract. The Journal of The Textile Institute 107, 525-530.

  • Saleh, S.M., El-Badry, K., 2012, Dyeing of cotton/nylon blended fabric to a solid shade in one bath. Global Journal of Science Frontier Research 12.

  • Shah, B., Shah, A., Singh, R., 2009, Sorption isotherms and kinetics of chromium uptake from wastewater using natural sorbent material. International Journal of Environmental Science & Technology 6, 77-90.

  • Shahin, M., 2015, The influence of cationization on the dyeing performance of cotton fabrics with direct dyes. International Journal of Engineering Research and Applications 5, 62-70.

  • Srikulkit, K., Pornsuriyasak, P., 1998, Method of chemical modification of cellulosic fibers to improve their dyeability with reactive dyes. J Sci Res Chula Univ 23, 143-153.

  • Sundrarajan, M., Gandhi, R.R., Rukmani, A., Selvam, S., Suresh, J., Gowri, S., 2012, Chitosan and cyclodextrin modification on cellulosic fabric for enhanced natural dyeing. Chemical science transactions 1, 440-446.

  • Temmerman, E., Leys, C., 2005, Surface modification of cotton yarn with a DC glow discharge in ambient air. Surface and coatings technology 200, 686-689.

  • Tutak, M., Oktay Özdemir, A., 2011, Reactive dyeing of cationized cotton: effects on the dyeing yield and the fastness properties. Journal of applied polymer science 119, 500-504.

  • Wang, X.-y., Liu, Y., 2014, The dyeing dynamics and structure of modified cotton fabric with cationic chicken feather keratin agent. Textile Research Journal 84, 561-571.

  • Xie, K., Hou, A., Sun, Y., 2007, Chemical and morphological structures of modified novel cellulose with triazine derivatives containing cationic and anionic groups. Carbohydrate polymers 70, 285-290.

  • Xie, K., Hou, A., Wang, X., 2008, Dyeing and diffusion properties of modified novel cellulose with triazine derivatives containing cationic and anionic groups. Carbohydrate polymers 72, 646-651.

  • ZHANG, J., 2005, New developing trends for dyestuff industry at home and abroad [J]. Dyeing and Finishing 4.

  • Zvinowanda, C., Okonkwo, J., Shabalala, P., Agyei, N., 2009, A novel adsorbent for heavy metal remediation in aqueous environments. International Journal of Environmental Science & Technology 6, 425-434.

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