Effects of Modifying Agents on the Dyeability of Cotton Fabric using Malachite Green Dye

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Abstract

Changes in thermodynamic parameters as a result of modifying agents on dye uptake of cotton fabric using malachite green (MG) dye was investigated in this study. Five modifying agents {Acetic acid (CH3COOH), hydrated Sodium carbonate (Na2CO3.10H2O), Sodium Chloride (NaCl), Ammonium sulphate ((NH4)2SO4) and Hydrogen peroxide (H2O2)} were used on cotton fabric. The equilibrium exhaustions (%E) were determined before and after modification of the cotton fabric at different concentrations which were 88.24%, 80%, 77.14%, 65.10% and 30.88% for CH3COOH, NaCl, (NH4)2SO4, Na2CO3.10H2O and H2O2 respectively. The results also showed a correlation between the standard affinity(-Δμθ) of dye on cotton fabric and the equilibrium exhaustion. The values of entropy (ΔSθ) and enthalpy (ΔHθ) change revealed the feasibility (spontaneity) and exothermic nature of the reaction. The optimum parameters were attained in acidic solution (CH3COOH) at the highest temperature (70 °C) of dyeing as it showed the highest % efficiency of 88.24%. This work established that modification of cotton fabric with modifying agents is one of the best route to improve the affinity between dye and fabric as it reduces stress, amount of dyes wasted in dyeing, time required to achieve satisfactory results leading to a cost effective environmental friendly approach in the field of cotton dyeing.

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  • Adebayo G. Adekola F. Olatunji G. Bello I. 2010 Some thermodynamic parameters of two indigenous mineral dyes applied on wool material. Bulletin of Pure & Applied Sciences 29 77.

  • Baltazar-Y-Jimenez A. Bismarck A. 2007 Surface modification of lignocellulosic fibres in atmospheric air pressure plasma. Green Chemistry 9 1057-1066.

  • Bashar M.M. Khan M.A. 2013 An overview on surface modification of cotton fiber for apparel use. Journal of Polymers and the Environment 21 181-190.

  • Bello I. Bello K. Peters O. Bello O. 2009 Synthesis Spectroscopic Thermodynamic And Dyeing Properties Of Disperse Dyes Derived From 2-Amino-4-Trifluoromethylbenzothiazole. Report and Opinion 1 58-66.

  • Bello I. A. Peters O. A. Nkeonye P. O. and Sunmonu O. K. 2002 Kinetics and Thermodynamics Studies of an Acid Dye on Modified Nylon 6 Fabrics. J. Pure Appl. Sci. 5: 309-314.

  • Bello I.A. Giwa A.-r.A. Aderinto S.O. Olabintan A. 2013 Effect Of Position of Substituents on the Exhaustion and Thermodynamic Parameters of 6 Monoazo Acid and Disperse Dyes on Nylon 6.

  • Bello I. A. Peters O. A. Giwa A. A. Abdul-Hammed M. Adeoye D. O. 2014 Effect of modifying agents on percentage equilibrium exhaustion of an acid dye on nylon fabric Australian J. Basic Appl. Sci. 8 (1) 552-559

  • El-Molla M. Badawy N. AbdEl-Aal A. El-Bayaa A. El-Shaimaa H. 2011 Dyeability of cationised cotton and nylon 6 fabrics using acid dyes.

  • Fang L. Zhang X. Ma J. Sun D. Zhang B. Luan J. 2015 Ecofriendly cationic modification of cotton fabrics for improving utilization of reactive dyes. RSC Advances 5 45654-45661.

  • Fang L. Zhang X. Sun D. 2013 Chemical modification of cotton fabrics for improving utilization of reactive dyes. Carbohydrate polymers 91 363-369.

  • Gharbani P. Tabatabaii S. Mehrizad A. 2008 Removal of Congo red from textile wastewater by ozonation. International Journal of Environmental Science & Technology 5 495-500.

  • Goyal P. Sharma P. Srivastava S. Srivastava M. 2008 Saraca indica leaf powder for decontamination of Pb: removal recovery adsorbent characterization and equilibrium modeling. International Journal of Environmental Science & Technology 5 27-34.

  • Hasani M. Westman G. Potthast A. Rosenau T. 2009 Cationization of cellulose by using N-oxiranylmethyl-N-methylmorpholinium chloride and 2-oxiranylpyridine as etherification agents. Journal of applied polymer science 114 1449-1456.

  • Hyde K. Dong H. Hinestroza J.P. 2007 Effect of surface cationization on the conformal deposition of polyelectrolytes over cotton fibers. Cellulose 14 615-623.

  • Igwe J.C. Abia A. Ibeh C. 2008 Adsorption kinetics and intraparticulate diffusivities of Hg As and Pb ions on unmodified and thiolated coconut fiber. International Journal of Environmental Science & Technology 5 83-92.

  • Kamel M. El Zawahry M. Ahmed N. Abdelghaffar F. 2009 Ultrasonic dyeing of cationized cotton fabric with natural dye. Part 1: Cationization of cotton using Solfix E. Ultrasonics Sonochemistry 16 243-249.

  • Kawee S. and Papapida P. 1998 Method of Chemical Modification of Cellulosic Fibers to improve their dyeability with reactive dyes J. Sci. Res. Chula. Univ. 23 (2): 143-153

  • Khattri S. Singh M. 1999 Colour removal from dye wastewater using sugar cane dust as an adsorbent. Adsorption science & technology 17 269-282.

  • Liu Z.-T. Yang Y. Zhang L. Liu Z.-W. Xiong H. 2007 Study on the cationic modification and dyeing of ramie fiber. Cellulose 14 337-345.

  • Ma W. Zhang S. Tang B. Yang J. 2005 Pretreatment of cotton with poly (vinylamine chloride) for salt-free dyeing with reactive dyes. Coloration Technology 121 193-197.

  • Mahbubul B. M. and Khan M.A. 2013 An Overview on Surface Modification of Cotton Fiber for Apparel Use J Polym Environ 21 181-190.

  • Mansour R. Farouk M. and Bechir1 E. M. 2014 Dyeing Properties of Cationized and non Cationized Cotton Fabrics Dyed with Vitis vinifera L. Leaves Extract Middle-East. J. Sci. Res. 21 (9)1600-1604.

  • Micheal M. Tera F. Ibrahim S. 2002 Effect of chemical modification of cotton fabrics on dyeing properties. Journal of applied polymer science 85 1897-1903.

  • Rattanaphani S. Chairat M. Bremner J.B. Rattanaphani V. 2007 An adsorption and thermodynamic study of lac dyeing on cotton pretreated with chitosan. Dyes and pigments 72 88-96.

  • Rym M. Farouk M. Bechir E.M. 2016 Dyeing properties of cationized and non-cationized cotton fabrics dyed with Vitis vinifera L. leaves extract. The Journal of The Textile Institute 107 525-530.

  • Saleh S.M. El-Badry K. 2012 Dyeing of cotton/nylon blended fabric to a solid shade in one bath. Global Journal of Science Frontier Research 12.

  • Shah B. Shah A. Singh R. 2009 Sorption isotherms and kinetics of chromium uptake from wastewater using natural sorbent material. International Journal of Environmental Science & Technology 6 77-90.

  • Shahin M. 2015 The influence of cationization on the dyeing performance of cotton fabrics with direct dyes. International Journal of Engineering Research and Applications 5 62-70.

  • Srikulkit K. Pornsuriyasak P. 1998 Method of chemical modification of cellulosic fibers to improve their dyeability with reactive dyes. J Sci Res Chula Univ 23 143-153.

  • Sundrarajan M. Gandhi R.R. Rukmani A. Selvam S. Suresh J. Gowri S. 2012 Chitosan and cyclodextrin modification on cellulosic fabric for enhanced natural dyeing. Chemical science transactions 1 440-446.

  • Temmerman E. Leys C. 2005 Surface modification of cotton yarn with a DC glow discharge in ambient air. Surface and coatings technology 200 686-689.

  • Tutak M. Oktay Özdemir A. 2011 Reactive dyeing of cationized cotton: effects on the dyeing yield and the fastness properties. Journal of applied polymer science 119 500-504.

  • Wang X.-y. Liu Y. 2014 The dyeing dynamics and structure of modified cotton fabric with cationic chicken feather keratin agent. Textile Research Journal 84 561-571.

  • Xie K. Hou A. Sun Y. 2007 Chemical and morphological structures of modified novel cellulose with triazine derivatives containing cationic and anionic groups. Carbohydrate polymers 70 285-290.

  • Xie K. Hou A. Wang X. 2008 Dyeing and diffusion properties of modified novel cellulose with triazine derivatives containing cationic and anionic groups. Carbohydrate polymers 72 646-651.

  • ZHANG J. 2005 New developing trends for dyestuff industry at home and abroad [J]. Dyeing and Finishing 4.

  • Zvinowanda C. Okonkwo J. Shabalala P. Agyei N. 2009 A novel adsorbent for heavy metal remediation in aqueous environments. International Journal of Environmental Science & Technology 6 425-434.

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