Synthesis and Characterization of Antimony Telluride for Thermoelectric and Optoelectronic Applications

Open access


Antimony telluride (Sb2Te3) is an intermetallic compound crystallizing in a hexagonal lattice with R-3m space group. It creates a c lose packed structure of an ABCABC type. As intrinsic semiconductor characterized by excellent electrical properties, Sb2Te3 is widely used as a low-temperature thermoelectric material. At the same time, due to unusual properties (strictly connected with the structure), antimony telluride exhibits nonlinear optical properties, including saturable absorption. Nanostructurization, elemental doping and possibilities of synthesis Sb2Te3 in various forms (polycrystalline, single crystal or thin film) are the most promising methods for improving thermoelectric properties of Sb2Te3. Applications of Sb2Te3 in optical devices (e.g. nonlinear modulator, in particular saturable absorbers for ultrafast lasers) are also interesting. The antimony telluride in form of bulk polycrystals and layers for thermoelectric and optoelectronic applications respectively were used. For optical applications thin layers of the material were formed and studied. Synthesis and structural characterization of Sb2Te3 were also presented here. The anisotropy (packed structure) and its influence on thermoelectric properties have been performed. Furthermore, preparation and characterization of Sb2Te3 thin films for optical uses have been also made.

[1] D.M. Rowe ed.: CRC Handbook of Thermoelectrics, Ch 3 (CRC Press, 1995).

[2] R. Zybała, M. Schmidt, K. Kaszyca et al., J. Electron. Mater. 45 (10), 5223-5231 (2016).

[3] R. Zybala, K.T. Wojciechowski, AIP Conf. Proc. 1449, 393 (2012) doi: 10.1063/1.4731579.

[4] M.J. Kruszewski, R. Zybala, L. Ciupinski, et al., J. Electron. Ma ter. 45 (3), 1369 (2016).

[5] P. Nieroda, R. Zybala, K.T. Wojciechowski, AIP Conf. Proc. 1449, 199 (2012), doi: 10.1063/1.4731531.

[6] H. Zhang, C.X. Liu, X.L. Qi, et al., Nat. Phys. 5 (6), 438-442 (2009).

[7] J. Liu, S. Liu, J. Wei, Appl. Phys. Lett. 97, 261903 (2010).

[8] J. Sotor, G. Sobon, W. Macherzynski, et al., Opt. Mater. Express 4 (1), 1-6 (2014).

[9] J. Boguslawski, G. Sobon, R, Zybala, et al., Opt. Express 23 (22), 29014-29023 (2015).

[10] J. Bogusławski, G. Sobon, K. Tarnowski, et al., Opt. Eng. 55 (8) 081316, (2016).

[11] C. Tan, Q. Wang, X. Fu, Opt. Mater. Express 4 (10), 2016-2025 (2014).

[12] Wei Jingsong, Optical Nonlinear Absorption and Refraction of Semiconductor Thin Films. In Nonlinear Super-Resolution Nano-Optics and Applications, Springer Berlin Heidelberg, 61-105 (2015).

[13] G. Sobon, Photon. Res. 3 (2), A56-A63 (2015).

[14] W. Richter, H. Kohler, C.R. Becker, Phys. Status Solidi 84, 619-628 (1977).

[15] G. Hao, X. Qi, Y. Fan, et al., Appl. Phys. Lett. 102, 013105 (2013).

[16] K.A. Kokh, V.V. Atuchin, T.A. Gavrilova, et al., Solid State Commun. 177, 16-19 (2014).

[17] S.M. Souza, D.M. Triches, J.C. De Lima, et al., Physica B 405, 2807-2817 (2010).

[18] S.D. Jackson, Nat. Photonics 6, 423-431 (2012).

Archives of Metallurgy and Materials

The Journal of Institute of Metallurgy and Materials Science and Commitee on Metallurgy of Polish Academy of Sciences

Journal Information

IMPACT FACTOR 2016: 0.571
5-year IMPACT FACTOR: 0.776

CiteScore 2016: 0.85

SCImago Journal Rank (SJR) 2016: 0.347
Source Normalized Impact per Paper (SNIP) 2016: 0.740

Cited By


All Time Past Year Past 30 Days
Abstract Views 0 0 0
Full Text Views 525 382 32
PDF Downloads 192 165 11