Microstructure and Properties of Ni and Ni/Al2O3 Coatings Electrodeposited at Various Current Densities

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The study presents investigations of an influence of various direct current densities on microstructure, residual stresses, texture, microhardness and corrosion resistance of the nickel coatings electrodeposited from modified Watt’s baths. The properties of obtained coatings were compared to the nano-crystalline composite Ni/Al2O3 coatings prepared under the same plating conditions. The similarities and differences of the obtained coatings microstructures visible on both their surfaces and cross sections and determined properties were presented. The differences in the growth character of the Ni matrix and in the microstructural properties were observed. All electrodeposited Ni and Ni/Al2O3 coatings were compact and well adhering to the steel substrates. The thickness and the microhardness of the Ni and Ni/Al2O3 deposits increased significantly with the current density in the range 2 - 6 A/dm2. Residual stresses are tensile and they reduced as the current density increased. The composite coatings revealed better protection from the corrosion of steel substrate than pure nickel in solution 1 M NaCl.

[1] Technical Tidbits a publication by BRUSH WELLMAN ENGINEERED MATERIALS vol. 4, 4 (2002).

[2] A. Góral, J.Deda E. Bełtowska-Lehman, B. Major, Analysis of Strengths, Weaknesses, Opportunities and Threats (SWOT) and Prerequisite Tree (PT) of Selected Technologies for Coating and Layer Production. Arch Metall Mater 53, 979-984 (2008).

[3] J. Du, L. Xu, B. Chen, L. De, Electrodeposition of nanocrystalline Ni-W coatings with citric acid system, J Nanosci Nanotechnol 13, 690-693 (2013).

[4] P. Prioteasa, L. Anicai, T. Visan, Synthesis and corrosion characterization of electrodeposited Ni-Mo alloys obtained from aqueous solutions, U.P.B. Sci Bull B 72, 11-24 (2010).

[5] H. Zhang, X. J. Zhang, Y. K. Zhang, Structure and Properties of electroless Nickel-Boron alloys, Plat Surf Finish 80, 80-84 (1993).

[6] M. Srivastava, V.K. William Grips, K.S. Rajam, Electrochemical deposition and tribological behaviour of Ni and Ni-Co metal matrix composites with SiC nano-particles, Appl Surf Sci 253, 3814-3824 (2007).

[7] M. Verest, J.P. Bonino, M. Brieu, A. Rouset, Thermomechanical properties of Ni-Al2O3 metal matrix composites produced by electroforming, Mat Sci Eng A 191, 165-169 (1995).

[8] S.T. Aruna, V. Ezhil Selvi, V.K. William Grips, K.S. Rajam, Corrosion- and wear-resistant properties of Ni-Al2O3 composite coatings containing various forms of alumina, J. Appl Electrochem 41, 461-468 (2011).

[9] H. Gul, F. Kilic, S. Aslan, A. Alp, H. Akbulut, Characteristics of electro-co-deposited Ni-Al2O3 nano-particle reinforced metal matrix composite (MMC) coatings, Wear 267, 976-990 (2009).

[10] A.B. Vidrine, E.J. Podlaha, Composite electrodeposition of ultrafine γ-alumina particles in nickel matrices. Part I: Citrate and chloride electrolytes, J. Appl Electrochem 31, 461-468 (2001).

[11] X.Y. Wei, Z.G. Zhu, P.D. Prewett, K. Jiang, Fabrication of Ni-Al2O3 composite microcomponent by electroforming, Microelectron Eng 84, 1256-1259 (2007).

[12] S-L.Kuo, Y-C. Chen, M-D. Ger, W-H. Hwu, Nano-particles dispersion effect on Ni/Al2O3 composite coatings, Mater Chem Phys 86, 5-10 (2004).

[13] I. Corni, R.J. Chater, A.R. Boccaccini, Electro co-deposition of Ni-Al2O3 composite coatings, J. Mater Sci 47, 5361-5373 (2012).

[14] A. Góral, M. Nowak, K. Berent, B. Kania, Influence of current density on microstructure and properties of electrodeposited nickel-alumina composite coatings. J Alloy Compd 615, S406-S410 (2014).

[15] G. Parida, D. Chaira, M. Chopkar, A. Basu, Syntesis and characterization of Ni-TiO2 composite coatings by electro-codeposition, Surf Coat Tech 205, 4871-4879 (2011).

[16] R. Arghavanian, N. Parvini-Ahmadi, The effect of coelectrodeposited ZrO2 particles on the microstructure and corrosion resistance of Ni coatings, J Solid State Electrochem 15, 2199-2204 (2011).

[17] I. Garcia, A. Conde, G. Langelaan, J. Fransaer, J.P. Celis, Improved corrosion resistance through microstructural modifications induced by codepositing SiC-particles with electrolytic nickel, Corros Sci 45, 1173-1189 (2003).

[18] R.K. Saha, T.I. Khan, Effect of applied current on the electrodeposited Ni-Al2O3 composite coating, Surf Coat Tech 205, 890-895 (2010).

[19] B. Szczygiel, M. Kolodziej, Corrosion resistance of Ni/Al2O3 coatings in NaCl solution, T I Met Finish 83, 181-187 (2005).

[20] S. Skrzypek, A. Baczmański, W. Ratuszek, E. Kusior, New approach to stress analysis based on grazing incidence X-ray diffraction, J Appl Crystallogr 34 427-435 (2001).

[21] Autolab-Application Note no 016

Archives of Metallurgy and Materials

The Journal of Institute of Metallurgy and Materials Science and Commitee on Metallurgy of Polish Academy of Sciences

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