Synthesis Of Magnesium-Aluminum Layered Double Hydroxides By Mechanochemical Method And Its Solid State Reaction Kinetics

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Abstract

A mechanochemical method is developed in preparing magnesium-aluminum-layered double hydroxides (MgAl-LDHs). This approach includes activation process and diffusion process. In order to verify the LDHs structure and study the reaction kinetics, X-ray diffraction (XRD) patterns, inductively coupled plasma(ICP) and physical adsorption instrument were characterized. The results show that activation time can change the surface of particles and affect the reaction grade. During the diffusion process, reaction time is the most important factor. The reaction energy (ΔQ) was calculated that is 6kJ/mol.

[1] F. Delorme, A. Seron, M. Bizi, et al., Journal Material Science 41, 4876 (2006).

[2] NobuoIyi, Takayoshi Sasaki, Applied Clay Science 42, 246 (2008).

[3] Toshiyuki Hibino, Hitoshi Ohya, Applied Clay Science 4, 578 (2009).

[4] X. ZhiPing, L. GuoQing, Chem. Mater. 17, 1055 (2005).

[5] S. Yanqing, Z. Yuming, W. Zhiqiang, et al., Applied Surface Science 255, 6372 (2009).

[6] L. Feng, D. Xue, Structure Bond 119, 193 (2006).

[7] V.V. Boldyrev, Russian Chemical Reviews. 75, 177 (2006).

[8] F.Kh. Urakaev, V.V. Boldyrev, Powder Technology 107, 93 (2000).

[9] A.A. Politov, III International Conference “Fundamental Basea of Mechanochemical Technology”. Novosibirsk, 2009:89.

Archives of Metallurgy and Materials

The Journal of Institute of Metallurgy and Materials Science and Commitee on Metallurgy of Polish Academy of Sciences

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