Removal of 4-chlorophenol from aqueous solution by granular activated carbon/nanoscale zero valent iron based on Response Surface Modeling

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Abstract

The phenolic compounds are known as priority pollutants, even in low concentrations, as a result of their toxicity and non-biodegradability. For this reason, strict standards have been established for them. In addition, chlorophenols are placed in the 38th to 43th in highest priority order of toxic pollutants. As a consequence, contaminated water or wastewaters with phenolic compounds have to be treated before discharging into the receiving water. In this study, Response Surface Methodology (RSM) has been used in order to optimize the effect of main operational variables responsible for the higher 4-chlorophenol removal by Activated Carbon-Supported Nanoscale Zero Valent Iron (AC/NZVI). A Box-Behnken factorial Design (BBD) with three levels was applied to optimize the initial concentration, time, pH, and adsorbent dose. The characterization of adsorbents was conducted by using SEM-EDS and XRD analyses. Furthermore, the adsorption isotherm and kinetics of 4-chlorophenol on AC and AC/NZVI under various conditions were studied. The model anticipated 100% removal efficiency for AC/NZVI at the optimum concentration (5.48 mg 4-chlorophenol/L), pH (5.44), contact time (44.7 min) and dose (0.65g/L). Analysis of the response surface quadratic model signified that the experiments are accurate and the model is highly significant. Moreover, the synthetic adsorbent is highly efficient in removing of 4-chlorophenol.

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  • Akar T. Ozcan A. S. Tunali S. & Ozcan A. (2008). Biosorption of a textile dye (Acid Blue 40) by cone biomass of Thuja orientalis: Estimation of equilibrium thermodynamic and kinetic parameters Bioresource Technology 99 8 pp. 3057-3065.

  • Asghar A. Abdul Raman A.A. & Daud W.M.A.W. (2014). A comparison of central composite design and Taguchi method for optimizing Fenton process The Scientifi c World Journal vol. 2014 pp. 1-14.

  • Babuponnusami A. & Muthukumar K. (2012). Removal of phenol by heterogenous photo electro Fenton-like process using nano-zero valent iron Separation and Purifi cation Technology 98 pp. 130-135.

  • Bayramoğlu G. & Arıca M.Y. (2008). Enzymatic removal of phenol and p-chlorophenol in enzyme reactor: Horseradish peroxidase immobilized on magnetic beads Journal of Hazardous Materials 156 1-3 pp. 148-155.

  • Bayramoglu G. Gursel I. Tunali Y. & Arica M.Y. (2009). Biosorption of phenol and 2-chlorophenol by Funaliatrogii pellets Bioresource Technology 100 10 pp. 2685-2691.

  • Cai H.-M. Chen G.-J. Peng C.-Y. Zhang Z.-Z. Dong Y.-Y. Shang G.-Z. Zhu X.-H. Gao H.-J. & Wan X.-C. (2015). Removal of fl uoride from drinking water using tea waste loaded with Al/Fe oxides: A novel safe and effi cient biosorbent Applied Surface Science 328 pp. 34-44.

  • Cheng W. Dastgheib S.A. & Karanfi l T. (2005). Adsorption of dissolved natural organic matter by modifi ed activated carbons Water Research 39 11 pp. 2281-2290.

  • Choe S. Lee S.-H. Chang Y.-Y. Hwang K.-Y. & Khim J. (2001). Rapid reductive destruction of hazardous organic compounds by nanoscale Fe0 Chemosphere 42 4 pp. 367-372.

  • Ciobanu G. Barna S. & Harja M. (2016). Kinetic and equilibrium studies on adsorption of Reactive Blue 19 dye from aqueous solutions by nanohydroxyapatite adsorbent Archives of Environmental Protection 42 2 pp. 3-11.

  • Doddapaneni K.K. Tatineni R. Potumarthi R. & Mangamoori L.N. (2007). Optimization of media constituents through response surface methodology for improved production of alkaline proteases by Serratia rubidaea Journal of Chemical Technology and Biotechnology 82 8 pp. 721-729.

  • Eckenfelder W.W. (1989). Industrial water pollution control McGraw-Hill 1989.

  • Fakhri A. (2015). Investigation of mercury (II) adsorption from aqueous solution onto copper oxide nanoparticles: optimization using response surface methodology Process Safety and Environmental Protection 93 pp. 1-8.

  • Foo K. & Hameed B. (2010). Insights into the modeling of adsorption isotherm systems Chemical Engineering Journal 156 1 pp. 2-10.

  • Handbook E. (1998). Advanced Photochemical Oxidation Processes Offi ce of Research and Development Washington DC 20460.

  • Jafari A. Mahvi A. H. Godini H. Rezaee R. & Hosseini S.S. (2014). Process optimization for fl uoride removal from water by Moringa Oleifera seed extract Fluoride 47 pp. 152-160.

  • Joo S.H. Feitz A.J. & Waite T.D. (2004). Oxidative degradation of the carbothioate herbicide molinate using nanoscale zero-valent iron Environmental Science & Technology 38 7 pp. 2242-2247.

  • Kanel S.R. Manning B. Charlet L. & Choi H. (2005). Removal of arsenic (III) from groundwater by nanoscale zero-valent iron Environmental Science & Technology 39 5 1291-1298.

  • Kassaee M.Z. Motamedi E. Mikhak A. & Rahnemaie R. (2011). Nitrate removal from water using iron nanoparticles produced by arc discharge vs. reduction Chemical Engineering Journal 166 2 pp. 490-495.

  • Lai C. & Chen C.-Y. (2001). Removal of metal ions and humic acid from water by iron-coated fi lter media Chemosphere 44 5 pp. 1177-1184.

  • Lin K.-Y. A. Liu Y.-T. & Chen S.-Y. (2016). Adsorption of fl uoride to UiO-66-NH2 in water: stability kinetic isotherm and thermodynamic studies Journal of Colloid And Interface Science 461 pp. 79-87.

  • Mangal H. Saxena A. Rawat A.S. Kumar V. Rai P.K. & Datta M. (2013). Adsorption of nitrobenzene on zero valent iron loaded metal oxide nanoparticles under static conditions Microporous and Mesoporous Materials 168 pp. 247-256.

  • Michaux F. Carteret C. Stébé M.-J. & Blin J.-L. (2013). Investigation of properties of mesoporous silica materials based on nonionic fl uorinated surfactant using Box-Behnken experimental designs Microporous and Mesoporous Materials 174 pp. 135-143.

  • Moradi M. Fazlzadehdavil M. Pirsaheb M. Mansouri Y. Khosravi T. & Sharafi K. (2016). Response surface methodology (RSM) and its application for optimization of ammonium ions removal from aqueous solutions by pumice as a natural and low cost adsorbent Archives of Environmental Protection 42 2 pp. 33-43.

  • Mourabet M. El Rhilassi A. El Boujaady H. Bennani-Ziatni M. El Hamri R. & Taitai A. (2012). Removal of fl uoride from aqueous solution by adsorption on Apatitic tricalcium phosphate using Box-Behnken design and desirability function Applied Surface Science 258 10 pp. 4402-4410.

  • Myers R.H. Montgomery D.C. & Anderson-Cook C.M. (2016). Response surface methodology: process and product optimization using designed experiments John Wiley & Sons 2016.

  • Navarro A.E. Portales R.F. Sun-Kou M.R. & Llanos B.P. (2008). Effect of pH on phenol biosorption by marine seaweeds Journal of Hazardous Materials 156 1-3 pp. 405-411.

  • Ponder S.M. Darab J.G. & Mallouk T.E. (2000). Remediation of Cr (VI) and Pb (II) aqueous solutions using supported nanoscale zero-valent iron Environmental Science & Technology 34 12 pp. 2564-2569.

  • Qin Q. Wang Q. Fu D. & Ma J. (2011). An effi cient approach for Pb(II) and Cd(II) removal using manganese dioxide formed in situ Chemical Engineering Journal 172 1 pp. 68-74.

  • Ra J.S. Oh S.-Y. Lee B.C. & Kim S.D. (2008). The effect of suspended particles coated by humic acid on the toxicity of pharmaceuticals estrogens and phenolic compounds Environment International 34 2 pp. 184-192.

  • Rappoport Z. (2004). The Chemistry of Phenols 2 Volume Set John Wiley & Sons 2004.

  • Rice E.W. Baird R.B. Eaton A.D. & Clesceri L.S. (2012). Standard methods for the examination of water and wastewater American Public Health Association American Water Works Association Water Environment Federation 2012.

  • Rodríguez M. (2003). Fenton and UV-vis based advanced oxidation processes in wastewater treatment: Degradation mineralization and biodegradability enhancement Universitat de Barcelona 2003.

  • Sądej W. Żołnowski A.C. & Marczuk O. (2016). Content of phenolic compounds in soils originating from two long-term fertilization experiments Archives of Environmental Protection 42 4 pp. 104-113.

  • Souza A.S. Dos Santos W.N. & Ferreira S.L. (2005). Application of Box-Behnken design in the optimisation of an on-line pre- -concentration system using knotted reactor for cadmium determination by fl ame atomic absorption spectrometry Spectrochimica Acta Part B: Atomic Spectroscopy 60 5 pp. 737-742.

  • Tepe O. & Dursun A.Y. (2008). Combined effects of external mass transfer and biodegradation rates on removal of phenol by immobilized Ralstonia eutropha in a packed bed reactor Journal of Hazardous Materials 151 1 pp. 9-16.

  • Tseng H.-H. Su J.-G. & Liang C. (2011). Synthesis of granular activated carbon/zero valent iron composites for simultaneous adsorption/dechlorination of trichloroethylene Journal of Hazardous Materials 192 2 pp. 500-506.

  • Vadivelan V. & Kumar K.V. (2005). Equilibrium kinetics mechanism and process design for the sorption of methylene blue onto rice husk Journal of Colloid And Interface Science 286 1 pp. 90-100.

  • W.H.O. 1989. Chlorophenols other than pentachlorophenol. Geneva: World Health Organization.

  • Wu F.-C. Wu P.-H. Tseng R.-L. & Juang R.-S. (2011). Preparation of novel activated carbons from H2SO4-Pretreated corncob hulls with KOH activation for quick adsorption of dye and 4-chlorophenol Journal of Environmental Management 92 3 pp. 708-713.

  • Wu J. & Yu H.-Q. (2007). Biosorption of 24-dichlorophenol by immobilized white-rot fungus Phanerochaete chrysosporium from aqueous solutions Bioresource Technology 98 2 pp. 253-259.

  • Yaneva Z.L. Koumanova B.K. & Georgieva N.V. (2012). Linear and nonlinear regression methods for equilibrium modelling of p-nitrophenol biosorption by Rhizopus oryzae: Comparison of error analysis criteria Journal of Chemistry 2013.

  • Yazdanbakhsh A.R. & Hashempour Y. (2015). Experimental design and response surface modeling for optimization of humic substances removal by activated carbon: A kinetic and isotherm study Journal of Advances in Environmental Health Research 3 2 pp. 91-101.

  • Zhang W.-H. Quan X. & Zhang Z.-Y. (2007). Catalytic reductive dechlorination of p-chlorophenol in water using Ni/Fe nanoscale particles Journal of Environmental Sciences 19 3 pp. 362-366.

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