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Magnetic recykling of complex catalysts immobilized on thiol-functionalized polymer supports

Abstract

In this work, the application of the thiol-functionalized epoxy resin encapsulated on magnetic core as supports for palladium catalysts is reported. The study focuses on obtaining of heterogeneous catalysts which can be separated by magnetic field. Palladium complex catalyst [PdCl2(PhCN)2] has been heterogenized by anchoring to these supports via ligand exchange reaction. The characterization of polymeric supports and heterogenized palladium catalysts has involved research methods like time-of-flight secondary ion mass spectrometry (TOF-SIMS), scanning electron microscopy (SEM) and nitrogen BET surface area measurements. The activity and stability during long-term use of the investigated catalytic systems were tested in a Heck and hydrogenation reaction. The influence of the type of thiols used as epoxy hardeners and the morphology of the supports on the catalytic properties of epoxy-supported palladium catalysts was discussed.

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Synthesis and antibacterial properties of Fe3O4-Ag nanostructures

one-pot synthesis of Ag–Fe 3 O 4 nanocomposite: a magnetically recyclable and efficient catalyst for epoxidation of styrene. Chem. Commun. 29, 3414–3416. DOI: 10.1039/B805737K. 22. Moosavi, R., Afkhami, A. & Madrakian, T. (2015). A Simple cyanide sensing probe based on Ag/Fe 3 O 4 nanoparticles. Anal. Chem. 5, 15886–15891. DOI: 10.1039/C4RA14806A. 23. Jäger, M., Schubert, S., Ochrimenko, S., Fischer, D., & Schubert, U.S. (2012). Branched and linear poly(ethylene imine)-based conjugates: synthetic modification, characterization, and application. Chem

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