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In Europe, the genus Ramonda is represented with three species: Ramonda nathaliae, Ramonda serbica and Ramonda myconi. The first two are endemic Balkan species that are distributed also in Kosovo. These species grow in limestone as well as serpentine substrates, forming chasmophytic vegetation. The species Ramonda nathaliae is found in Macedonia, Greece, Serbia and in two localities in Kosovo, in the Sharri Mountains (Luboten and Gotovushë). R. nathaliae forms the following plant associations in the serpentines of Macedonia: Asplenio­Ramondetum nathaliae and Scorzonero-Ramondetum nathaliae, and the Achilleo­Ramondetum nathaliae in limestone substrates. Ostrya carpinifolia is charateristic species in Querco pubescentis-Ostryetum carpinifoliae, Ostryo-Fagetum, Querco-Ostryetum carpinifoliae and Corylo colurnae-Ostryetum carpinifoliae. This paper presents plant communities of Ramonda nathaliae and Ostrya carpinifolia in a limestone habitat, where the proposed new plant association named Ramondo­Ostryetum carpinifoliae ass. nova. is described. This plant community belongs to the class Quercetea pubescentis, order Quercetalia pubescenti­petraeae and alliance Fraxino orni­Ostryion. It was found and described on the limestone substrate on Mt. Luboteni (at 960–982 m a.s.l.).