An attempt has been made to recycle Styrofoam waste to a novel functional polymer, Phenyl thiosemicarbazone surface (PTS). Polystyrene (PS) obtained from Styrofoam waste was acetylated and then condensed to PTS by reacting it with 4-Phenyl-3-thiosemicarbazide ligand and characterized by FT-IR spectroscopy and elemental analysis. Synthesized PTS was applied successfully for the treatment of lead contaminated water by batch extraction method. Sorption variables were optimized (pH 8, adsorbent dose 53mg, initial Pb(II) ion concentration 10mgl-1 and agitation time 90min) by factorial design approach. Lead uptake by PTS was found much sensitive to the pH of Pb(II) ion solution. The maximum removal (99.61%) of Pb(II) ions was achieved at optimum conditions. The Langmuir and D-R isotherm study suggested the monolayer, favorable (RL=0.0001-0.01) and chemisorption (E=20.41±0.12kJmol-1) nature of the adsorption process. The sorption capacity of PTS was found to be 45.25±0.69mgg-1. The FT-IR spectroscopy study showed the involvement of nitrogen and sulphur of thiosemicarbazone moiety of PTS for the uptake of Pb(II) ions by five membered chelate formation.
Surendra Singh, Anshuman Sahai, S.C. Katyal and Navendu Goswami
We have synthesized zinc-copper ferrite (ZCFO) employing exploding wire technique (EWT). The X-ray diffraction (XRD) data confirm the formation of single phase spinel ZCFO, which is in good agreement with Fourier transform infrared spectroscopy (FT-IR), UV-Vis, and Raman spectroscopic analyses. It is also clearly seen in the SEM micrographs that the grains in ZCFO ferrite are very rough, which allows adsorption of gas like oxygen and therefore, the material can behave as active sensing surface. The size range of the grains in prepared sample is of 200 nm to 500 nm. The FT-IR spectrum of the nanocomposite consists of two broad bands, one at 580.4 cm−1 due to M–O stretching mode at the tetrahedral site and the other at 400.7 cm−1 due to M–O stretching mode at the octahedral site. The nanoparticles show a UV-Vis absorption band in the wavelength region of 400 nm to 700 nm. The energy band gap for the prepared nanomaterial was estimated to be 3.16 eV. Thus, the ferrite nanocomposite prepared by EWT is optically active. According to present literature, Raman spectroscopy study on zinc-copper ferrite system has not been reported till date. By suitable attributing various Raman modes, we have further confirmed the formation of ZCFO nanophase through the present novel approach.
Anu Dhupar, Suresh Kumar, Vandana Sharma and J.K. Sharma
In the present work, mixed structure Zn(S,O) nanoparticles have been synthesized using solution based chemical coprecipitation technique. Two different zinc sources (Zn(CH3COO)2·2H2O and ZnSO4·7H2O) and one sulfur source (CSNH2NH2) have been used as primary chemical precursors for the synthesis of the nanoparticles in the presence and absence of a capping agent (EDTA). The structural, morphological, compositional and optical properties of the nanoparticles have been analyzed using X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), Fourier transmission infra-red (FT-IR) and UV-Visible (UV-Vis) spectroscopy. XRD revealed the formation of mixed phases of c-ZnS, h-ZnS and h-ZnO in the synthesized nanoparticles. The surface morphology was analyzed from SEM micrographs which showed noticeable changes due to the effect of EDTA. EDX analysis confirmed the presence of zinc, sulfur and oxygen in Zn(S,O) nanoparticles. FT-IR spectra identified the presence of characteristic absorption peaks of ZnS and ZnO along with other functional group elements. The optical band gap values were found to vary from 4.16 eV to 4.40 eV for Zn(S,O) nanoparticles which are higher in comparison to the band gap values of bulk ZnS and ZnO. These higher band gap values may be attributed to the mixed structure of Zn(S,O) nanoparticles.
K. Ramarao, B. Rajesh Babu, B. Kishore Babu, V. Veeraiah, K. Rajasekhar, B. Ranjith Kumar and B. Swarna Latha
In this work, Ni substituted magnesium spinel ferrites having general formula Mg1−xNixFe2O4 (where x = 0.0, 0.1, 0.15, 0.2, 0.25 and 0.3) were synthesized by standard solid state reaction method. All the samples were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), vibrating sample magnetometer (VSM), DC resistivity measurements. X-ray diffraction analysis confirmed the single spinel phase. The lattice constant decreased with increasing Ni content due to the difference in the ionic radii of Mg2+ and Ni2+ ions. The FT-IR spectra reveled two prominent frequency bands in the wave number range of 400 cm−1 to 600 cm−1, which confirmed the cubic spinel structure of obtained compound and completion of chemical reaction. Magnetic studies revealed that the saturation magnetization increased with the substitution of Ni. The increase in magnetization was explained on the basis of distribution of magnetic and non-magnetic cations among A and B sites of the spinel lattice. A significant influence of cation distribution on DC electrical resistivity and activation energy was observed.
Lead sulphide (PbS) nanopowder was synthesized by a simple soft chemical route using lead nitrate and thiourea as precursor salts. The as-synthesized nanopowder was characterized by XRD, SEM, EDX, FT-IR, PL, Raman and magnetic measurements. XRD studies reveal the polycrystalline nature of the powder. The powder exhibits face-centered cubic structure with a strong (2 0 0) preferential orientation. The presence of Pb and S in the powder is confirmed by energy dispersive X-ray analysis. The peaks observed at 1112 cm-1 and at 606 cm-1 in the FT-IR spectrum are related to heteropolar diatomic molecules of PbS. The Raman peak shift at 173 cm-1 might have originated from the combination of longitudinal and transverse acoustic phonon modes associated with PbS crystal. The M-H loop confirms the paramagnetic nature of the as-synthesized PbS nanopowder. The nanopowder has significant antimicrobial activity against certain bacteria and fungi strains which make it suitable as antimicrobial agent against pathogenic microorganisms.
Talat Zeeshan, Safia Anjum, Hina Iqbal and Rehana Zia
A series of copper substituted cobalt chromium ferrites, CuxCo1 - xCr0.5Fe1.5O4 (x = 0, 0.2, 0.4, 0.6, 0.8, 1.0) has been synthesized, by employing powder metallurgy method. Calcination of the samples has been carried out for 24 hours at 1100 °C. The resultant materials have been investigated by using a variety of techniques, including X-ray diffractometry (XRD), Fourier transform infrared spectroscopy (FT-IR), vibrating sample magnetometer (VSM)), scanning electron microscopy (SEM), and ultraviolet visible spectroscopy (UV-Vis). The XRD patterns confirmed that all compositions had a cubic spinel structure with a single phase and the lattice parameter was found to increase with increasing copper concentration. FT-IR spectroscopy has been used for studying the chemical bonds in the spinel ferrite. Shifting of the bands ν1 and ν2 has been observed. It has been revealed from VSM analysis that saturation magnetization and coercivity decrease with rising the Cu+2 doping. Magnetic properties have been explained on the basis of cation distribution. Scanning electron microscopy (SEM) has been used to study the surface morphology of prepared samples. UV-Vis analysis revealed the optical absorption of the samples. An increase in band gaps has been observed with increasing copper concentration in the sample.
Yufeng Ma, Xiang Geng, Xi Zhang, Chunpeng Wang and Fuxiang Chu
A novel 9, 10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO) graft γ-amino propyl triethoxy silane (KH550) was synthesized and introduced on the surface of wood fiber. Finally DOPO-g-KH550 treated wood fiber (DKTWF) was used to prepare DKTWF composite phenolic foams (DKTWFCPF). The structures of DOPO-g- KH550 was acknowledged by Fourier transform infrared (FT-IR) and nuclear magnetic resonance (1H-NMR). The structures of DKTWF were confirmed by FT-IR. Compared with wood fiber, the diffraction peaks’ position was basically unchanged, but the crystallinity was slightly increased and thermal stability were dramatically improved, T5% and Tmax increased by 21.9o and 36.1o respectively. But the char yield (800o) was slightly reduced. With the dosage of DKWF, there were different degrees of improvement including the mechanical properties, flame retardancy and microstructure of DKTWFCPF. Comprehensive analysis, the interfacial compatibility was significantly improved between DKTWF and phenolic resin, and the suitable content of DKTWF was 4%.
Organic/inorganic hybrid materials consisting of quantum dots and conjugate polymers are important for the application in light emitting devices. In the present work, we have studied the effect of CdS and CdS/ZnO nanoparticle addition on the structure and fluorescence properties of spin coated PVK (poly(N-vinyl carbozole)) nanocomposite films. CdS nanoparticles were synthesized by simple co-precipitation technique and ZnO shell was grown on the CdS nanoparticles by simple wet chemical approach. The nanoparticles and the hybrid nanocomposites have been characterized by using XRD, SEM, FT-IR, optical absorption and fluorescence spectroscopic techniques. The absorption peak for pure PVK remains at 345.5 nm accompanied with minor hump ~480 nm resulting from the incorporation of nanoparticles. It has been observed that the addition of nanoparticles to the hybrid material results in the enhancement of fluorescence intensity at 410 nm to 450 nm spectral regions. These results are important for the development of new light emitting devices at low fabrication costs.
Polypropylene/carbon nanotubes (PP/CNTs) nancomposites were prepared with a single screw extruder by adding maleic anhydride-grafted poplypropylene (PP-g-MAH) as compatibilizer to polypropylene (PP) with different amounts of carbon nanotubes (CNTs) in the range of 0.1–0.7 wt.%. Structure and morphology of the prepared samples were examined by Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), polarizing light microscopy (PLM) and X-ray diffraction (XRD). The results showed that PP spherulites decreased in size when CNTs were introduced into the polymer. Mechanical properties of the samples were also studied. Tensile tests showed that with increasing amount of CNTs the strain at break decreased whereas the Young’s modulus was improved of 16.41 % to 36.05 % and tensile strength of 36.67 % to 64.70 % compared to pristine PP. The SEM microphotographs showed that majority of the CNTs were dispersed individually and oriented along the shear flow direction.
Modified PVC (M-PVC) material with suppressed migration and low glass transition temperature was prepared via click reaction of a monooctyl phthalate derivative. Chemical structure and composition of M-PVC were characterized by FT-IR, 1H NMR and element analysis. Thermal stability, glass transition temperature and migration stability of M-PVC were studied with TGA, DSC and migration tests, respectively. The study showed that M-PVC exhibited poor thermal stability, and low glass transition temperature of 66.0°C. No migration was found in distilled water, 10% (v/v) ethanol, 30% (w/v)acetic acid and petroleum ether. The PVC material is expected to preparing PVC products in the areas with high migration resistance requirement.