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  • Author: Tomasz Pikula x
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Abstract

(BiFeO3)1-x-(BaTiO3)x solid solutions with x = 0.1–0.4 and 0.7 were investigated. The ceramics were prepared by mechanical activation technology and subsequent heat treatment. As was proved by X-ray diffraction, increase of BaTiO3 concentration causes a change in the crystalline structure from the rhombohedral structure characteristic of BiFeO3 to a cubic one. 57Fe Mössbauer spectroscopy allowed observation of a gradual transformation from an ordered spin structure of Fe3+ ions to the paramagnetic state with an increase of x.

Abstract

In this research, the mechanical activation method is proposed as an alternative process of preparation of the (BiFeO3)1-x-(BaTiO3)x solid solutions with various concentrations of barium titanate (x = 0.1÷0.9). However, mechanical milling itself does not allow obtaining the desired products and additional thermal treatment is needed to complete the solid-state reaction. In the present studies, X-ray diffraction and 57Fe Mössbauer spectroscopy were applied as complementary methods in order to study the structural and magnetic properties of materials. The investigations revealed that an increase of BaTiO3 concentration causes changes in the crystalline and hyperfine magnetic structure of the studied (BiFeO3)1-x-(BaTiO3)x system.

Abstract

The simple co-precipitation method was used to prepare AgxFeO2 delafossite with non-stoichiometric silver concentration in the range of x = 0.05-1. The obtained material was investigated using X-ray powder diffraction and 57Fe Mössbauer spectroscopy at room temperature. The structural and hyperfi ne interaction parameters were recognized in relation with decreasing silver concentration. The study revealed that the delafossite structure of AgxFeO2 was maintained up to x = 0.9; as the range of silver concentration was decreased to 0.05 ≤ x ≤ 0.8, a mixture of AgFeO2, Fe2O3 or/and FeOOH was formed.