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T. Sak and M. Kucharski

Abstract

Density of the copper-rich corner of the ternary Cu-Pb-Fe alloys was determined with the dilatometric method. Investigated alloys had constant copper content equal to 0.9, 0.8 and 0.7 mole fraction, and varied iron concentration up to 0.1 mole fraction. A model predicting the density of ternary solution from knowledge of density of pure component and the excess of molar volume for limiting binaries is proposed.

Open access

M. Kucharski, P. Madej, M. Wedrychowicz, T. Sak and W. Mróz

Abstract

This study is devoted to tellurium recovery from sodium carbonate slag, formed in the fire refining process of crude silver. The slag was modified by silica additions and then reduced by carbon oxide. The degree of the slag modification was defined by the parameter kw:

where:ni- the mole numbers of silica, sodium carbonate and sodium oxide. The compositions of the investigated slag determined by the parameter kw and the mole fraction of the tellurium oxide (xTeO2 ) are given in the following Table.

The reduction of tellurium was very fast for all the investigated slags, which was manifested by an almost complete conversion of CO into CO2. Unfortunately, at the same time, a side reaction took place, and as a results sodium telluride was formed, which reported to the slag:

(Na2O)slag + Te(g) + CO = (Na2Te)slag + CO2

The tellurium content in the reduced slag decreases as the parameter kw increases, and only the slag with the kw equal unity was suitable for the tellurium recovery in form of dusts, containing more than 76 wt-% tellurium.