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  • Author: Nisar Ahmed x
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Abstract

The Zhob Ophiolite is divided into three detached blocks including the Omzha block. The Omzha block is mapped and divided into lithological units such as ultramafic rock, mafic-felsic rock, and volcanic–volcaniclastic–pelagic rocks. These units are quite deformed and mixed up and are associated with one another by thrust faults. Petrography and geochemistry divide them into gabbro, diorite, plagiogranite, pheno-tephrite and trachy-andesite basalt, trachy basalt, chert, limestone, and mudstone. The ultramafic rocks are dominantly serpentinized harzburgite, dunite, and a minor lherzolite. Petrography of peridotite shows that it may be depleted in nature and may have residual after processes such as partial melting and the melt-rock reaction of a lherzolitic source. The gabbroic rocks are less well-developed and highly deformed. They are cross-cut by diorite, plagiogranite and anorthosite’ intrusions. The gabbro may be the plutonic section of Omzha block’ crust while the intermediate-felsic igneous rocks may have formed by the anataxis of crustal gabbro. The volcanic–volcaniclastic–pelagic rocks unit may be corrected with Bagh complex found underneath the Muslim Bagh Ophiolite. The metamorphic sole rocks of Omzha block are highly deformed and dismembered are comprising of metamorphic facies such as amphibolite, quartz-mica schist, and greenschist.

Abstract

The electronic structure and magnetic properties of Mn doped zinc blende cadmium sulfide Cd1-xMnxS (x = 6.25 %) have been studied using spin-polarized density functional theory within the framework of Generalized Gradient Approximation (GGA), its further corrections including Hubbard U interactions (GGA + U) and a model for exchange and correlation potential Tran Blaha modified Becke-Johnson (TB-mBJ). Ferromagnetic interactions have been observed between Mn atoms via S atom due to strong p-d hybridization. The magnetic moments on Mn and its neighboring atoms have also been studied in detail using different charge analysis techniques. It has been observed that p-d hybridization reduced the value of local magnetic moment of Mn in comparison to its free space charge value and produced small local magnetic moments on the nonmagnetic S and Cd host sites. The magnetocrystalline anisotropy in [1 0 0] and [1 1 1] directions as well as exchange splitting parameters Noα and Noβ have been analyzed to confirm that ferromagnetism exists. We conclude that the ferromagnetic phase in Mn-doped CdS is not stable in “near” configuration but it is stable for “far” configuration. Mn doped CdS is a p-type semiconductor and the d-states at the top of the valence band edge give a very useful material for photoluminescence and magneto-optical devices.

Abstract

The Gwal mélange is mapped on a large scale and is divided into the lithological units such as ultramafic, mafic, volcanic, volcanoclastic rocks, pelagic sediments and ophicarbonates. Petrographically, the mapped rocks are classified as harzburgite, dunite, wehrlite, serpentinite, gabbro, basalt, and andesite. These rocks are quite deformed and altered into the secondary minerals. Harzburgite is a layered mantle peridotite consists of olivine and orthopyroxene while dunite lacks the presence of any pyroxene. Serpentinite is the secondary product after peridotite is the product of post magmatic stages. The mesh structure is usually observed when olivine is completely altered to serpentine. The volcanic rocks are structurally sheeted and pillow type while the volcanoclastic rocks are essentially hyaloclastites associated with pelagic sediments. The Ophicarbonate is composed of serpentinite fragments and carbonate minerals, most probably calcite. Minor to trace amounts of opaque minerals are also present in association with major components. The gabbros may be a fragment of the main crustal rocks and have been formed in a magma chamber by fraction crystallization. The origin of ophicarbonate may be due to gas seeps originated by mantle or as the surficial process where ultramafic rocks and carbonates are mixed through processes of gravity, tectonic crushing and sedimentary reworking. The Gwal mélange may the southern extension of Bagh Complex found beneath the Muslim Bagh Ophiolite. The mantle peridotite of the mélange is much like that of the Khanozai peridotite and may represent its detached blocks. Volcanic and volcanoclastic rocks may be the representatives of the uppermost part of ophiolite crust which might have trimmed off from subducting slab and are, now, part of the Gwal accretionary wedge. The mélange may have tectonically emplacement over the Indian platform sediments along with overlying the ophiolite sheet during the Late Cretaceous.