Stefan Demcak, Magdalena Balintova, Maria Demcakova, Inga Zinicovscaia, Nikita Yushin and Marina V. Frontasyeva
The heavy metal removal from wastewater is very important due to their persistent character in aquatic environment. The use of wooden sawdust is emerging as a potential alternative to the existing conventional technologies for the removal of metal ions from aqueous solutions. The aim of this work is to study the Cu(II) removal of from water by unconventional waste products including the wooden sawdust of poplar, cherry, spruce and hornbeam. The FT-IR spectra of the studied wooden sawdust confirmed the presence of functional groups that have potential for heavy metal binding. The highest efficiency of Cu(II) removal was observed for poplar wooden sawdust at static (86 %) and dynamic (88 %) adsorption experiments. Data obtained by neutron activation analysis revealed that ion exchange is also a mechanism of metal removal by the selected wooden sawdust.
Stefan Demcak, Magdalena Balintova, Maria Hurakova, Marina V. Frontasyeva, Inga Zinicovscaia and Nikita Yushin
Some kinds of natural organic materials have a potential for removal of heavy metal ions from wastewater. It is well known that cellulosic waste materials or by-products can be used as cheap adsorbents in chemical treatment process. In this paper, poplar wood sawdust were used for removal of Cu(II), Zn(II) and Fe(II) ions from model solutions with using the static and dynamic adsorption experiments. Infrared spectrometry of poplar wood sawdust confirmed the presence of the functional groups which correspond with hemicelluloses, cellulose and lignin. At static adsorption was achieved approximately of 80 % efficiency for all treated model solutions. Similar efficiency of the adsorption processes was reached after 5 min at dynamic condition. The highest efficiency of Cu(II) removal (98 %) was observed after 30 min of dynamic adsorption. Changes of pH values confirmed a mechanism of ion exchange on the beginning of the adsorption process.
Inga Zinicovscaia, Mira Aničić Urošević, Konstantin Vergel, Ecaterina Vieru, Marina V. Frontasyeva, Igor Povar and Gheorghe Duca
For the first time active moss biomonitoring was used to assess trace element deposition in the capital of the Republic of Moldova, Chisinau. Moss Sphagnum girgensohnii samples were exposed in bags at three sites of Chisinau from October, 2016 to March, 2017. The content of 30 elements: Na, Mg, Cl, K, Ca, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Zn, As, Br, Rb, Mo, Sr, Sb, Ba, La, Ce, Cs, Hf, Th, Cu, Cd, Pb, and U in the exposed and unexposed mosses was determined by neutron activation analysis and atomic absorption spectrometry. According to the relative accumulation factor, the most abundant elements in the samples were V, Cr, Fe, Ba, La, As, Sb, U, and Pb. Such elements as Cl, K, and Rb were depleted from the moss tissue during the time of exposure. Principal component analysis was used to identify and characterize different pollution sources. The obtained results indicate that the use of S. girgensohnii moss bags is a simple and inexpensive technique to monitor major and trace element content in the air of urban area.
Inga Zinicovscaia, Alexey Safonov, Varvara Tregubova, Victor Ilin, Liliana Cepoi, Tatiana Chiriac, Ludmila Rudi and Marina V. Frontasyeva
Spirulina platensis biomass is widely applied for different technological purposes. The process of lanthanum, chromium, uranium and vanadium accumulation and biosorption by Spirulina platensis biomass from single- and multi-component systems was studied. The influence of multi-component system on the spirulina biomass growth was less pronounced in comparison with the single-component ones. To trace the uptake of metals by spirulina biomass the neutron activation analysis was used. In the experiment on the accumulation the efficiency of studied metal uptake changes in the following order: La(V) > Cr(III) > U(VI) > V(V) (single-metal solutions) and Cr(III) > La(V) > V(V) > U(VI) (multi-metal system). The process of metals biosorption was studied during a two-hour experiment. The highest rate of metal adsorption for single-component systems was observed for lanthanum and chromium. While for the multi-component system the significant increase of vanadium and chromium content in biomass was observed. In biosorption experiments the rate of biosorption and the Kd value were calculated for each metal. Fourier transform infrared spectroscopy was used to identify functional groups responsible for metal binding. The results of the present work show that spirulina biomass can be implemented as a low-cost sorbent for metal removal from industrial wastewater.
Wael Badawy, Olesya Ye. Chepurchenko, Hussein El Samman and Marina V. Frontasyeva
Assessment of the environmental impact of El Sadat City, a Cairo satellite, known for its clustered enterprises, on the neighbourhood water supply El Manashi Tawfikia Canal was undertaken through soil analysis. A total of 20 agricultural soil samples were collected along the El Manashi Tawfikia Canal. Neutron activation analysis was implemented to determine heavy metal contents of such elements as As, Ba, Co, Cr, Ni, and Zn. Multivariate statistical analysis was applied to the results obtained. The metal pollution index and enrichment factor were calculated. It was shown that the content of toxic heavy metals in soil samples does not exceed the worldwide-published values, except arsenic which considerably exceeds normalized to the content of the same element in the Upper Continental Crust. The metal pollution index is high compared with the calculated ones for similar soil samples from the Nile Delta, and the enrichment factor varied from moderate to high enrichment (5 < EF > 10).
Chuks P. Eze, Olanrewaju Fatoba, Godfrey Madzivire, Tatyna M. Ostrovnaya, Leslie F. Petrik, Marina V. Frontasyeva and Alexander N. Nechaev
Epithermal neutron activation analysis along with ICP-OES, LA ICP-MS, and XRF were used to determine the elemental composition of coal fly ash from the Malta coal power station in the Mpumalanga province of South Africa. A total of 54 major, trace and rare earth elements were obtained by the four analytical techniques. The results were compared and the discrepancies discussed to show the merits and drawbacks of each of the techniques. It was shown that the elemental content of this particular coal fly ash are of the same order as the NIST standard reference material Coal Fly Ash 1633b.
Inga Zinicovscaia, Liudmila Rudi, Ana Valuta, Liliana Cepoi, Konstantin Vergel, Marina V. Frontasyeva, Alexey Safonov, Markus Wells and Dmitrii Grozdov
The cyanobacterium Nostoc linckia was used to study the biotechnology of selenium nanoparticles synthesis for the first time. The experimental conditions of the nanoparticle production by the studied cyanobacteria in aqueous cobalt selenite solutions were examined. Neutron activation analysis allowed characterization of the dynamics of accumulation of the total selenium quantity by Nostoc linckia. Scanning Electron Microscope images demonstrated extracellular formation of amorphous nanoparticles. Released selenium nanoparticles ranged in size from 10 to 80 nm. The changes of essential parameters of biomass (proteins, lipids, carbohydrates, and phycobilin) content during the nanoparticle formation were assessed. During the first 24 h of nanoparticle synthesis, a slight decline of proteins, lipids and carbohydrates content in the biomass was observed. The most extensive was the process of phycobilin degradation. Furthermore, all biochemical component content as well as an antioxidant activity of the biomass extracts significantly decreased. The obtained substance of Nostoc biomass with selenium nanoparticles may be used for medical, pharmaceutical and technological purposes.
Tamaz Kalabegishvili, Ivane Murusidze, Elena Kirkesali, Alexander Rcheulishvili, Ereri Ginturi, Nana Kuchava, Nanuli Bagdavadze, Eteri Gelagutashvili, Marina V. Frontasyeva, Inga Zinicovscaia, Sergey S. Pavlov and Andrey Y Dmitriev
The synthesis of gold and silver nanoparticles by the blue-green algae Spirulina platensis for medical purposes was studied. A complex of optical and analytical methods was used in order to characterize produced nanoparticles. It was shown that the extracellular formation of metal nanoparticles of spherical shape with sizes in the range between 8 and 40 nm (the average size of 20-30 nm) takes place. The characteristics of gold and silver nanoparticles in the Spirulina biomass were compared. The role of biosorption processes in the synthesis of nanoparticles was estimated by using equilibrium dialysis. A positive influence of sonication on the process of microbial synthesis and yield of nanoparticles were demonstrated. The neutron activation analysis and the atomic absorption spectrometry were applied for characterizing the dynamics of gold and silver nanoparticles formation in the Spirulina platensis biomass. The neutron activation analysis was used for studying the elemental content of the Spirulina platensis biomass.
Jacques Bezuidenhout, Nicole Dames, Alfred Botha, Marina V. Frontasyeva, Zoya I. Goryainova and Dmitry Pavlov
Invasive bivalve molluscs, Mediterranean mussels (Mytilus galloprovincialis) were used as sentinel biomonitors of pollution by inorganic contaminants in Saldanha Bay and the Langebaan Lagoon area of South Africa. Two complementary analytical techniques, ICP-MS and NAA, allowed for determination of concentrations of 31 major and trace elements including heavy metals and arsenic in the soft tissues of the mussels. Distinct seasonal patterns were found in the dynamics of these concentrations, with the mussels accumulating much more trace elements in winter than in the summer. In general, the mussels that grew naturally also demonstrated higher concentrations of As, Cd, Fe, Hg and Zn than those that were farmed. Fe showed the highest levels with a maximum concentration of 444 mg/kg followed by Zn with a maximum of 228 mg/kg. The concentrations of Mn and Pb were significantly higher in the Port of Saldanha close to the jetty where ores containing these metals are loaded in comparison with the other sampling sites. It was concluded that bivalve molluscs present themselves as effective biomonitors when assessing marine aquatic pollution by inorganic contaminants in the Saldanha Bay region.
Andrzej Kłos, Yulia A. Aleksiayenak, Zbigniew Ziembik, Małgorzata Rajfur, Dominik Jerz, Maria Wacławek and Marina V. Frontasyeva
The neutron activation analysis procedure was used to determine the concentration of 42 elements: Na, Mg, Al, Cl, K, Ca, Sc, V, Cr, Mn, Fe, Ni, Co, Zn, As, Se, Br, Rb, Sr, Zr, Nb, Mo, I, Ag, Cd, Sb, Ba, Cs, La, Ce, Nd, Sm, Eu, Tb, Yb, Hf, Ta, W, Au, Hg, Th, and U accumulated in mosses sampled for testing in September and October 2011 in the Opole Province (Southern Poland). Samples of different moss species were collected near the intersections of the grid lines marked on the map of the province. The distance between the points was approximately 20 km. The analysis of the results made it possible to identify the places of increased deposition of element-pollutants and to indicate the potential sources of emission. Factor analysis revealed four components, two of which are of definite anthropogenic origin. The possible sources of elements are local industry and farming, and distant heavy industry complexes. The results have demonstrated the increased content of Cr, Cd, Hg, and U in moss samples collected in agricultural areas located in the southern part of the province. It has been concluded that the industrial areas of Rybnik and Ostrava and Karvina Coal Basin may be the potential source of emission of these elements.