The paper concerns the research on self-organization of the surface of coating of hypoeutectic alloy Fe-Mn-C-B modified Si, Ni, Cr, Cu with friction with C45 steel. The coatings were obtained by arc welding using a flux-cored wire. Tests of resistance to wear were carried out for hypoeutectic coatings with use of the friction pair pin-on-disc in the conditions of sliding friction, in model lubricating environments. The surface-active (glycerol oil) and inactive (Vaseline grease) lubricant was used. Tribological tests carried out showed that cooperation of hypoeutectic alloy coating with counterbody of C45 steel with lubrication with surface-active lubricant results in a significant improvement in tribological properties than in case of the lubrication with surface-inactive lubricant. The resulting effect is related to the self-organization of friction surface. After deposition and wear resistance tests, the friction surface microstructure was analysed, as well as the surface and depth distribution of the elements.