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  • Author: Jerzy K. Garbacz x
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Jerzy K. Garbacz and Mariusz Kozakiewicz

Abstract

The analysis of Berezin and Kiselev’s concept assuming linear association of molecules in a localised adsorption monolayer on the homogeneous surface of a solid adsorbent was carried out. An inconsistency due to the lack of consideration of equilibrium concentration of free adsorption sites in the formulation of the expression for the association constant has been pointed out. It was shown that the correct form of this function leads to the final adsorption equation being identical to the specific case of the Fowler-Guggenheim equation. The obtained result has been generalised to cases of branched adsorbateadsorbate associations. A new adsorption equation limiting the association to at most the dimers has been introduced. Critical conditions for the two-dimensional condensation of the adsorption layer were determined. By applying the formalism of canonical ensemble, full equivalence of the phenomenological and statistical methods was demonstrated in the description of the intermolecular interactions in the localised adsorption monolayer.

Open access

Jerzy K. Garbacz, Jacek Cieściński, Jerzy Ciechalski, Ryszard Dąbkowski and Jolanta Cichowska

Abstract

This paper presents an analysis of thermal and oxygen conditions of the Charzykowskie Lake in the years 2014-2016 in the period from May to August. The measurements were carried out once a month, at points representing three different basins in the lake, and the temperatures and oxygen content dissolved in the water were recorded every 1m from the surface to the bottom at the deepest point of each basin. The changes in temperatures and content of dissolved oxygen were analysed in each of the representative measurement points for particular parts of the lake. It has been shown that the deficit of oxygen dissolved in the bottom layers of the water starts occurring by the beginning of the summer stagnation period, whereas at its peak (August) the anaerobic zone includes hypolimnion and part of the metalimnion. The hypothesis that the thickness of the thermal layers varies within the lake basin was confirmed. It was also shown that the oxygen content curve at representative points, in all years of research, evolves to the form of a clinograde at the peak of summer stagnation, where the concentration of dissolved oxygen decreases with the depth.

Open access

Jerzy K. Garbacz, Ewa Kopkowska and Barbara Rymian

Abstract

The subsequent stages of the process of formulation of the equation for gas adsorption on a homogenous surface of a solid adsorbent were presented based on the general expression for the canonical ensemble of the mobile single-component adsorption monolayer. The method of formulating the configuration integral of the proposed model was discussed in detail where the role both of the attraction and repulsion between adsorbed molecules was emphasised. The expression for the probability of finding a molecule in a specified point on a surface of an adsorbent was modified by determining its magnitude by the adsorbent concentration. The expression for the so-called effective surface of the adsorbent was obtained by adapting a two-dimensional analogue equation of state hard spheres – Van der Waals equation (2D-vdW) and Reis-Frisch-Lebowitz equation accordingly (2D-RFL). As a result, two new adsorption equations were formulated which differ in detail concerning the adsorbate-adsorbate repulsion. On each of these equations theoretical analysis was performed in terms of two-dimensional phase transformation. In both cases it was proved that the proposed solution allows for the presence of two-phase transformations of the first type which is the gas-liquid condensation and solidification liquid-solid. The verification of the given approach was supplemented by the description of the experimental data given in reference literature and by obtaining a very good correlation between the theory and experiment.

Open access

Jolanta Cichowska, Jerzy K. Garbacz and Jerzy Ciechalski

Abstract

This work is a preliminary pilot research aiming at defining the role of the Piechcin Diving Centre in the development of specialised tourism. Particular attention was paid to the various elements defining the quality of the services offered. The key aspects and reasons for which respondents visit the centre were also determined. Both the customer’s expectations of the organiser of this form of recreation were analysed, and research was made to help understand whether the time the customers spends at the centre facilitates a positive decision regarding the participation in diving trips in larger bodies of water, with particular consideration of the Baltic Sea. Different forms of cooperation between the centre and regional authorities in terms of promoting the region were also reviewed.