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  • Author: Hanna Kierzkowska-Pawlak x
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Determination of Kinetics in Gas-Liquid Reaction Systems. An Overview

The aim of this paper is to present a brief review of the determination methods of reaction kinetics in gas-liquid systems with a special emphasis on CO2 absorption in aqueous alkanolamine solutions. Both homogenous and heterogeneous experimental techniques are described with the corresponding theoretical background needed for the interpretation of the results. The case of CO2 reaction in aqueous solutions of methyldiethanolamine is discussed as an illustrative example. It was demonstrated that various measurement techniques and methods of analyzing the experimental data can result in different expressions for the kinetic rate constants.

Pressure swing absorption of carbon dioxide in n-methyl-2-pyrrolidone solutions

The mass transfer rates during CO2 absorption and desorption from N-methyl-2-pyrrolidone solutions were measured at 293.15 K in a baffled agitated reactor with a flat gas-liquid interface. Based on the measured values of pressure changes, the desorption rate was determined and compared to the absorption rate at the same driving force. Two distinct mechanisms of desorption were observed. The transition from bubbling to the diffusive desorption is found to be a function of the supersaturation ratio, pressure and the stirring speed.

Reaction Kinetics of Carbon Dioxide in Aqueous Diethanolamine Solutions Using the Stopped-Flow Technique

The pseudo-first-order rate constants (kOV) for the reactions between CO2 and diethanolamine have been studied using the stopped-flow technique in an aqueous solution at 293, 298, 303 and 313 K. The amine concentrations ranged from 167 to 500 mol·m-3. The overall reaction rate constant was found to increase with amine concentration and temperature. Both the zwitterion and termolecular mechanisms were applied to correlate the experimentally obtained rate constants. The values of SSE quality index showed a good agreement between the experimental data and the corresponding fit by the use of both mechanisms.

Abstract

The CO2 absorption process using aqueous amine solutions has been the most promising technique used for the removal of CO2 from gas streams in energy sector. In recent years, many researchers tested solutions which are composed of several compounds: a slow reacting tertiary amine- and a fast amine acting as an activator. In this paper, the CO2 absorption rate in an aqueous solution of N,N-diethylethanoloamine (DEEA) and activated solutions DEEA is investigated experimentally. The activators considered are sterically hindered amines: 2-amino-2-methyl-1-propanol (AMP), 2-amino-2-methyl-1,3-propanediol (AMPD) and N-methyl-1,3-propanediamine (MAPA) from the group of polyamines. The experiments were conducted over the temperature range of 303-333 K and the total amine concentration of 2 M. From the CO2 absorption experiments into mixed aqueous solutions of DEEA and MAPA, it was found that the addition of small amounts of MAPA into aqueous DEEA solutions has a significant effect on the enhancement of the CO2 absorption rate. The application of hindered amines: AMP or AMP as activators resulted in a marginally improvement of the absorption rate of CO2.