The isotope activity concentration of rocks and bottom sediments was evaluated based on the samples collected from sedimentation ponds and gangue repositories. Radium 226Ra, thorium 228Th and potassium 40K activities were measured by gamma spectrometry using high-purity germanium detector – HPGe 4020. The radiation effect resulting from the presence of natural radionuclides was estimated by radiological hazard indices such as f1 and f2 coefficients, radium equivalent, internal and external hazard indices and absorbed dose rate. Performed measurements and calculations have shown that the bottom sediments are most contaminated. They may pose a serious radiological hazard for present and future generations.